IV
.
D
.7. (
XVIII
.
A
.2.)
Bad Calculated Bond Lengths
List of molecules with calculated bond lengths that differ by more than 0.050 Å from experimental bond lengths.
Calculated at B2PLYP/6-31G(2df,p)
Species
Name
Bond type
Bond Length (Å)
Experimental
Calculated
Difference
Ne
2
Neon dimer
rNeNe
3.100
2.460
-0.640
NaK
Sodium Potassium
rNaK
3.589
3.477
-0.112
2 molecules.