IV
.
D
.7. (
XVIII
.
A
.2.)
Bad Calculated Bond Lengths
List of molecules with calculated bond lengths that differ by more than 0.050 Å from experimental bond lengths.
Calculated at M06-2X/3-21G*
Species
Name
Bond type
Bond Length (Å)
Experimental
Calculated
Difference
Ne
2
Neon dimer
rNeNe
3.100
2.910
-0.190
NaK
Sodium Potassium
rNaK
3.589
3.430
-0.159
CH
3
OCl
methyl hypochlorite
rCO
1.389
1.471
0.082
3 molecules.