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XIII.F.2. (III.B.7.b.) (IV.C.7.) (XVIII.B.2.)

Bad vibrational frequency predictions

Calculated frequencies that differ from experiment by more than 400 cm-1 or have a ratio with experiment outside of 0.7 to 1.2 are listed

Calculated vibrational frequencies ("theory" in table) are calculated at B3PW91/STO-3G
Calculated values were scaled by 0.885.

Species Name mode Symmetry Experiment Theory difference ratio
H2CO+ formaldehyde cation 2 A1 1675 1342 -333 1.248
CCl4 Carbon tetrachloride 2 E 217 178 -39 1.219
C3H4O2 β–Propiolactone 13 A' 513 417 -96 1.229
C3H4O2 β–Propiolactone 21 A" 113 167 54 0.678
HCOOH Formic acid 7 A' 625 496 -129 1.261
CH3COOH Acetic acid 11 A' 657 460 -197 1.428
CH3COOH Acetic acid 18 A" 93 55 -38 1.681
CH3OH Methyl alcohol 12 A" 200 362 162 0.553
CH3SOCH3 Dimethyl sulfoxide 7 A' 1102 903 -199 1.221
CH3SOCH3 Dimethyl sulfoxide 12 A' 308 244 -64 1.265
CH3SOCH3 Dimethyl sulfoxide 23 A" 333 244 -89 1.364
CH3SOCH3 Dimethyl sulfoxide 9 A' 1006 813 -193 1.237
CH3SOCH3 Dimethyl sulfoxide 11 A' 382 300 -82 1.275
CH3SOCH3 Dimethyl sulfoxide 22 A" 695 540 -155 1.287
C2H6O2S Dimethyl sulfone 5 A1 1121 871 -250 1.287
C2H6O2S Dimethyl sulfone 13 A2 326 182 -144 1.788
C2H6O2S Dimethyl sulfone 20 B1 262 95 -167 2.751
C2H6O2S Dimethyl sulfone 19 B1 396 251 -145 1.576
C2H6O2S Dimethyl sulfone 27 B2 465 252 -213 1.845
C2H6O2S Dimethyl sulfone 7 A1 703 525 -178 1.339
C2H6O2S Dimethyl sulfone 9 A1 294 199 -95 1.475
C2H6O2S Dimethyl sulfone 17 B1 1269 940 -329 1.350
C2H6O2S Dimethyl sulfone 26 B2 771 509 -262 1.514
C2H6O2S Dimethyl sulfone 6 A1 1013 745 -268 1.359
C2H6O2S Dimethyl sulfone 25 B2 958 784 -174 1.222
C2H6O2S Dimethyl sulfone 8 A1 496 263 -233 1.886
C2H6O2S Dimethyl sulfone 18 B1 986 777 -209 1.269
CH3CCl3 Ethane, 1,1,1-trichloro- 11 E 351 292 -59 1.201
CH3NH2 methyl amine 14 A" 1195 918 -277 1.301
HCN+ hydrogen cyanide cation 3 Π 760 624 -136 1.218
CH3CH2Cl Ethyl chloride 18 A" 251 208 -43 1.207
CH2F2 Methane, difluoro- 4 A1 529 437 -92 1.210
HNCO Isocyanic acid 5 A' 577 438 -139 1.317
HNCO Isocyanic acid 6 A" 656 465 -191 1.412
C2H4O Ethylene oxide 7 A2 1300 1080 -220 1.204
CH3CHClCH3 Propane, 2-chloro- 27 A" 276 191 -85 1.443
CH3CHClCH3 Propane, 2-chloro- 15 A' 253 211 -42 1.200
CH3COCl Acetyl Chloride 15 A" 166 114 -52 1.457
CH3COCl Acetyl Chloride 10 A' 348 286 -62 1.217
CH3CHF2 Ethane, 1,1-difluoro- 11 A' 468 388 -80 1.206
CH2CF2 Ethene, 1,1-difluoro- 5 A1 550 441 -109 1.248
CCl2O Phosgene 4 B1 580 460 -120 1.261
CHF2Cl difluorochloromethane 4 A' 812 672 -140 1.208
CHF2Cl difluorochloromethane 9 A" 366 287 -79 1.274
CHF2Cl difluorochloromethane 6 A' 413 337 -76 1.225
CHF3 Methane, trifluoro- 3 A1 700 560 -140 1.251
CHF3 Methane, trifluoro- 6 E 507 391 -116 1.297
CBr2F2 Methane, dibromodifluoro- 3 A1 140 298 158 0.469
CF3Br Bromotrifluoromethane 2 A1 760 623 -137 1.219
CF3Br Bromotrifluoromethane 6 E 306 247 -59 1.239
CF3Br Bromotrifluoromethane 5 E 547 431 -116 1.271
CFCl3 Trichloromonofluoromethane 6 E 241 193 -48 1.250
CFCl3 Trichloromonofluoromethane 3 A1 350 281 -69 1.244
CF2Cl2 difluorodichloromethane 3 A1 458 373 -85 1.228
CF2Cl2 difluorodichloromethane 9 B2 446 348 -98 1.280
CF2Cl2 difluorodichloromethane 4 A1 262 199 -63 1.314
CF2Cl2 difluorodichloromethane 5 A2 322 249 -73 1.294
CF2Cl2 difluorodichloromethane 7 B1 437 357 -80 1.224
CF3Cl Methane, chlorotrifluoro- 3 A1 476 370 -106 1.286
CF3Cl Methane, chlorotrifluoro- 5 E 563 436 -127 1.291
CF3Cl Methane, chlorotrifluoro- 6 E 350 259 -91 1.350
CF3Cl Methane, chlorotrifluoro- 2 A1 781 643 -138 1.215
CF4 Carbon tetrafluoride 2 E 435 318 -117 1.369
CF4 Carbon tetrafluoride 4 T2 631 474 -157 1.330
CHOCH(CH3)CH3 Propanal, 2-methyl- 16 A' 632 482 -150 1.312
CHOCH(CH3)CH3 Propanal, 2-methyl- 32 A" 227 186 -41 1.221
CHOCH(CH3)CH3 Propanal, 2-methyl- 31 A" 351 287 -64 1.222
CHOCH(CH3)CH3 Propanal, 2-methyl- 17 A' 395 311 -84 1.269
CH2ClCHClCH3 Propane, 1,2-dichloro- 27 A 108 89 -19 1.219
CH2ClCHClCH3 Propane, 1,2-dichloro- 25 A 250 204 -46 1.228
CH2ClCHClCH3 Propane, 1,2-dichloro- 26 A 203 169 -34 1.204
CHClCCl2 Trichloroethylene 9 A' 178 137 -41 1.298
CHClCCl2 Trichloroethylene 8 A' 277 230 -47 1.202
CH3COOCH3 methyl acetate 17 A' 303 241 -62 1.257
CH3COOCH3 methyl acetate 24 A" 607 487 -120 1.246
CH3COOCH3 methyl acetate 26 A" 136 94 -42 1.442
CH3COOCH3 methyl acetate 25 A" 187 156 -31 1.201
CH3COOCH3 methyl acetate 27 A" 110 44 -66 2.487
CH3COOCH3 methyl acetate 16 A' 429 356 -73 1.205
C6H5NO2 Nitrobenzene 36 B2 265 161 -104 1.650
C6H5NO2 Nitrobenzene 11 A1 851 707 -144 1.204
C6H5NO2 Nitrobenzene 13 A1 399 315 -84 1.268
C6H5NO2 Nitrobenzene 35 B2 531 428 -103 1.241
C6H5NO2 Nitrobenzene 22 B1 675 541 -134 1.248
C6H5NO2 Nitrobenzene 24 B1 180 146 -34 1.231
C6H5CHO benzaldehyde 25 A' 224 172 -52 1.303
C6H4O2 parabenzoquinone 30 B3u 109 77 -31 1.405
CH2ClCH2Cl Ethane, 1,2-dichloro- 18 Bu 222 184 -38 1.208
CH2ClCH2Cl Ethane, 1,2-dichloro- 10 Au 123 91 -32 1.359
C3H3N acrylonitrile 15 A" 362 300 -62 1.208
C3H6O 2-Propen-1-ol 22 A 377 290 -87 1.299
C3H6O 2-Propen-1-ol 24 A 188 78 -111 2.424
C3H6O 2-Propen-1-ol 21 A 554 391 -163 1.418
CH3OCHO methyl formate 18 A" 130 86 -44 1.516
CH3OCHO methyl formate 12 A' 318 262 -56 1.215
CH3OCHO methyl formate 16 A" 1032 838 -194 1.232
C5H12 Pentane 23 A2 131 99 -32 1.326
C3H2N2 Malononitrile 6 A1 167 128 -39 1.308
C4H5N Pyrrole 16 B1 475 388 -87 1.224
C4H4N2 Succinonitrile 17 Bg 387 319 -68 1.213
C6H12 Cyclohexane 32 Eu 248 201 -47 1.233
C5H11N Piperidine 45 A" 254 209 -45 1.217
CH2C(CH3)CH3 1-Propene, 2-methyl- 21 B1 196 152 -44 1.291
CH2C(CH3)CH3 1-Propene, 2-methyl- 15 A2 193 127 -66 1.515
C2F4 Tetrafluoroethylene 6 B1u 558 446 -112 1.252
C2F4 Tetrafluoroethylene 9 B2u 218 156 -62 1.398
C2F4 Tetrafluoroethylene 7 B2g 508 354 -154 1.437
C2F4 Tetrafluoroethylene 3 Ag 394 316 -78 1.245
C2F4 Tetrafluoroethylene 4 Au 190 156 -34 1.220
CH3CH2CHO Propanal 15 A' 271 209 -62 1.296
CH3CH2CHO Propanal 24 A" 135 84 -51 1.604
C4H8O2 1,4-Dioxane 10 Ag 424 350 -74 1.211
C4H8O2 1,4-Dioxane 19 Au 288 201 -87 1.434
CO2 Carbon dioxide 3 Πu 667 439 -228 1.518
C2Cl4 Tetrachloroethylene 4 Au 110 87 -23 1.262
C2Cl4 Tetrachloroethylene 3 Ag 237 193 -44 1.226
C2Cl4 Tetrachloroethylene 9 B2u 176 140 -36 1.258
C5H8 Cyclopentene 18 A' 254 45 -209 5.669
C5H8 Cyclopentene 15 A' 904 750 -154 1.206
CHClCHCl Ethene, 1,2-dichloro-, (Z)- 5 A1 173 137 -36 1.264
CHClCHCl Ethene, 1,2-dichloro-, (E)- 12 Bu 250 199 -51 1.257
C4H8 cyclobutane 6 A1 199 84 -115 2.380
C3H4N2 1H-Pyrazole 21 A" 516 383 -133 1.347
C3H3NO Isoxazole 14 A" 1033 820 -213 1.260
C3H3NO Isoxazole 7 A' 1373 1137 -236 1.208
C3H4N2 1H-Imidazole 21 A" 539 422 -117 1.277
C2H3N3 1H-1,2,4-Triazole 14 A" 990 785 -205 1.262
C2H3N3 1H-1,2,4-Triazole 18 A" 640 413 -227 1.550
C2H3N3 1H-1,2,4-Triazole 15 A" 885 734 -151 1.206
CH2N4 1H-Tetrazole 15 A" 578 425 -153 1.361
CH2N4 1H-Tetrazole 12 A" 906 741 -165 1.222
C2H4O3 trioxolane124 21 B 193 86 -107 2.245
C4H4N2 Pyridazine 13 A2 421 318 -103 1.326
N2H4 Hydrazine 7 A 377 308 -69 1.225
CH2NN diazomethane 9 B2 420 315 -105 1.334
C2H5F fluoroethane 18 A" 243 190 -53 1.281
COFCl Carbonic chloride fluoride 6 A" 667 509 -158 1.311
COFCl Carbonic chloride fluoride 4 A' 501 404 -97 1.239
COFCl Carbonic chloride fluoride 3 A' 776 646 -130 1.201
COFCl Carbonic chloride fluoride 5 A' 415 325 -90 1.277
CF2O Carbonic difluoride 3 A1 584 442 -142 1.322
CF2O Carbonic difluoride 4 B1 774 561 -213 1.381
CF2O Carbonic difluoride 6 B2 626 478 -148 1.308
CF3CN Acetonitrile, trifluoro- 8 E 196 141 -55 1.392
CF3CN Acetonitrile, trifluoro- 7 E 463 361 -102 1.282
CF3CN Acetonitrile, trifluoro- 2 A1 1227 986 -241 1.245
CF3CN Acetonitrile, trifluoro- 4 A1 522 401 -121 1.301
NH2CN cyanamide 6 A' 487 397 -90 1.228
NH2CN cyanamide 9 A" 435 348 -87 1.250
HOCN cyanic acid 5 A' 460 361 -99 1.275
CH3CF3 Ethane, 1,1,1-trifluoro- 11 E 540 427 -113 1.265
CH3CF3 Ethane, 1,1,1-trifluoro- 5 A1 606 474 -132 1.278
CH3CF3 Ethane, 1,1,1-trifluoro- 6 A2 225 124 -101 1.821
CH3CF3 Ethane, 1,1,1-trifluoro- 12 E 365 288 -77 1.269
C4H6O2 2,3-Butanedione 10 Ag 369 295 -74 1.249
C4H6O2 2,3-Butanedione 30 Bu 250 176 -74 1.423
C4H6O2 2,3-Butanedione 21 Bg 240 62 -178 3.858
C4H6O2 2,3-Butanedione 9 Ag 614 461 -153 1.333
C4H6O2 2,3-Butanedione 16 Au 48 28 -20 1.710
CH2CO Ketene 6 B1 528 412 -116 1.283
CH2CO Ketene 9 B2 433 360 -73 1.202
OCS Carbonyl sulfide 3 Π 520 401 -119 1.297
C3H6O Oxetane 12 A2 986 789 -197 1.250
C3H6O Oxetane 8 A1 908 756 -152 1.202
C3O2 Carbon suboxide 7 Πu 61 114 53 0.533
C3O2 Carbon suboxide 5 Πg 573 456 -117 1.258
C3O2 Carbon suboxide 6 Πu 550 454 -96 1.212
C6H4F2 1,4-difluorobenzene 19 B2u 1633 1357 -276 1.203
CH3COF Acetyl fluoride 9 A' 598 493 -105 1.213
CH3COF Acetyl fluoride 15 A" 123 74 -49 1.663
CH3COF Acetyl fluoride 10 A' 420 346 -74 1.215
CH2CHCHClCH3 1-Butene, 3-chloro- 29 A 245 204 -41 1.203
C5H8 1,4-Pentadiene 31 B 721 564 -157 1.278
C5H8 1,4-Pentadiene 33 B 331 81 -250 4.104
C5H8 1,4-Pentadiene 15 A 421 336 -85 1.253
C5H8 1,4-Pentadiene 17 A 102 67 -35 1.519
C5H8 1,4-Pentadiene 16 A 137 265 128 0.518
C6H10 1,5-Hexadiene 29 Bg 264 131 -133 2.016
C6H10 1,5-Hexadiene 14 Ag 351 235 -116 1.494
C6H10 1,5-Hexadiene 20 Au 649 528 -121 1.228
COBr2 Carbonic dibromide 6 B2 512 335 -177 1.528
COBr2 Carbonic dibromide 4 B1 757 452 -305 1.675
CH3NO3 Methyl nitrate 11 A' 578 431 -147 1.341
CH3NO3 Methyl nitrate 10 A' 657 514 -143 1.279
CH3NO3 Methyl nitrate 12 A' 340 269 -71 1.266
CH3NO3 Methyl nitrate 16 A" 758 494 -264 1.534
CH3ONO Methyl nitrite 15 A" 186 138 -48 1.351
CH3SSCH3 Disulfide, dimethyl 13 A 117 77 -40 1.510
C6H8 1,4-Cyclohexadiene 19 B1u 108 84 -24 1.283
CO+ carbon monoxide cation 1 Σ 2214 1794 -420 1.234
C3H6O2 1,3-Dioxolane 6 A 1361 2815 1454 0.483
C3H6O2 1,3-Dioxolane 13 A 658 1171 513 0.562
C3H6O2 1,3-Dioxolane 4 A 1509 2917 1408 0.517
C3H6O2 1,3-Dioxolane 5 A 1480 2914 1434 0.508
C4H2N2 Fumaronitrile 18 Bu 148 119 -29 1.239
C3H7N Cyclopropylamine 27 A" 254 203 -51 1.250
C6H8 1,3,5-Hexatriene, (E)- 36 Bu 170 133 -37 1.278
C6H8 1,3,5-Hexatriene, (E)- 35 Bu 590 488 -102 1.210
C4N2 2-Butynedinitrile 3 Σg 692 547 -145 1.265
CaO Calcium monoxide 1 Σ 732 504 -228 1.453
GeO2 Germanium dioxide 2 Σu 1062 775 -286 1.369
GeO2 Germanium dioxide 3 Πu 196 110 -85 1.776
LiOH lithium hydroxide 3 Π 257 649 393 0.395
SiF2 Silicon difluoride 2 A1 278 228 -50 1.220
GeH3CH3 methyl germane 6 A2 157 121 -36 1.294
FCN Cyanogen fluoride 3 Π 451 369 -82 1.223
Si2H6 disilane 4 A1u 131 88 -43 1.489
CCl2 dichloromethylene 2 A1 335 270 -65 1.240
C5H10 Cyclopropane, 1,1-dimethyl- 39 B2 392 324 -68 1.212
CH3OCH2CN Methoxyacetonitrile 15 A' 243 154 -89 1.578
CH3OCH2CN Methoxyacetonitrile 24 A" 113 81 -32 1.399
CH3OCH2CN Methoxyacetonitrile 13 A' 586 483 -103 1.213
C2H5 Ethyl radical 9 A' 528 384 -144 1.374
C6H5O phenoxy radical 30 B2 446 364 -82 1.225
C6H5O phenoxy radical 6 A1 1397 1132 -265 1.234
CF2 Difluoromethylene 2 A1 667 552 -115 1.209
CF3 Trifluoromethyl radical 2 A1 701 539 -162 1.300
CF3 Trifluoromethyl radical 4 E 509 398 -111 1.278
C4H9N Cyclobutylamine 21 A' 174 98 -76 1.773
C4H9N Cyclobutylamine 36 A" 240 199 -41 1.204
SF6 Sulfur Hexafluoride 6 T2u 347 201 -146 1.724
SF6 Sulfur Hexafluoride 1 A1g 774 561 -213 1.380
SF6 Sulfur Hexafluoride 4 T1u 616 346 -269 1.777
SF6 Sulfur Hexafluoride 5 T2g 525 289 -236 1.818
CH2OH Hydroxymethyl radical 9 A 234 482 248 0.485
C6H8 1,3,5-Hexatriene, (Z)- 24 B1 358 88 -270 4.089
C6H8 1,3,5-Hexatriene, (Z)- 11 A1 1136 835 -301 1.361
C6H8 1,3,5-Hexatriene, (Z)- 19 A2 264 140 -124 1.892
SO2F2 Sulfuryl fluoride 1 A1 1269 832 -437 1.525
SO2F2 Sulfuryl fluoride 3 A1 544 254 -290 2.142
SO2F2 Sulfuryl fluoride 6 B1 885 638 -247 1.387
SO2F2 Sulfuryl fluoride 9 B2 553 270 -283 2.044
SO2F2 Sulfuryl fluoride 4 A1 385 184 -201 2.093
SO2F2 Sulfuryl fluoride 2 A1 848 600 -248 1.414
SO2F2 Sulfuryl fluoride 5 A2 388 186 -202 2.091
SO2F2 Sulfuryl fluoride 7 B1 539 241 -298 2.241
SO2F2 Sulfuryl fluoride 8 B2 1502 948 -554 1.584
C3H3 Propargyl radical 6 B1 687 536 -152 1.283
OH- hydroxide anion 1 Σ 3738 2491 -1248 1.501
OH Hydroxyl radical 1 Σ 3738 3202 -535 1.167
NF2 Difluoroamino radical 2 A1 573 476 -97 1.204
CCl+ carbon monochloride cation 1 Σ 1175 932 -243 1.261
CHOCHCHCH3 2-Butenal 18 A' 230 178 -52 1.289
C4H6 Methylenecyclopropane 17 B1 360 286 -74 1.260
SeO2 Selenium dioxide 2 A1 373 285 -88 1.309
SeO2 Selenium dioxide 3 B2 966 739 -227 1.307
SeO2 Selenium dioxide 1 A1 922 727 -195 1.268
SO2 Sulfur dioxide 3 B2 1362 941 -421 1.448
SO2 Sulfur dioxide 1 A1 1151 890 -262 1.294
SO2 Sulfur dioxide 2 A1 518 365 -153 1.419
SO3 Sulfur trioxide 1 A1' 1065 705 -360 1.510
SO3 Sulfur trioxide 2 A2" 498 157 -341 3.170
SO3 Sulfur trioxide 3 E' 1391 906 -485 1.536
SO3 Sulfur trioxide 4 E' 530 251 -279 2.110
C2Cl2+ dichloroacetylene cation 5 Πu 233 153 -80 1.519
ClFO3 Perchloryl fluoride 3 A1 549 169 -380 3.241
ClFO3 Perchloryl fluoride 5 E 589 179 -410 3.286
ClFO3 Perchloryl fluoride 6 E 405 131 -274 3.100
ClFO3 Perchloryl fluoride 1 A1 1061 546 -515 1.943
ClFO3 Perchloryl fluoride 4 E 1315 620 -695 2.122
ClFO3 Perchloryl fluoride 2 A1 715 414 -301 1.726
SiO2 silicon dioxide 2 Σu 1416 1168 -248 1.212
SiO2 silicon dioxide 3 Πu 273 105 -168 2.599
BF3 Borane, trifluoro- 2 A2" 691 560 -131 1.233
BF3+ boron trifluoride cation 3 E' 1662 635 -1027 2.619
BF3+ boron trifluoride cation 4 E' 411 -228 -639 -1.804
NaH sodium hydride 1 Σ 1172 1791 619 0.654
HCl+ hydrogen chloride cation 1 Σ 2674 2268 -405 1.179
PF5 Phosphorus pentafluoride 1 A1' 816 604 -212 1.351
PF5 Phosphorus pentafluoride 7 E' 174 78 -96 2.228
PF5 Phosphorus pentafluoride 4 A2" 575 375 -200 1.532
PF5 Phosphorus pentafluoride 5 E' 1024 812 -212 1.261
PF5 Phosphorus pentafluoride 8 E" 520 329 -191 1.580
PF5 Phosphorus pentafluoride 6 E' 533 340 -193 1.568
HF Hydrogen fluoride 1 Σ 4138 3474 -664 1.191
NH3+ ammonia cation 2 A2" 903 638 -265 1.416
H2SO4 Sulfuric acid 7 A 379 171 -208 2.219
H2SO4 Sulfuric acid 11 B 1157 906 -251 1.276
H2SO4 Sulfuric acid 13 B 558 257 -301 2.173
H2SO4 Sulfuric acid 3 A 1136 807 -329 1.408
H2SO4 Sulfuric acid 5 A 548 260 -288 2.108
H2SO4 Sulfuric acid 12 B 882 610 -272 1.445
H2SO4 Sulfuric acid 4 A 831 572 -259 1.453
H2SO4 Sulfuric acid 15 B 288 206 -81 1.394
H2SO4 Sulfuric acid 14 B 506 247 -259 2.048
H2SO4 Sulfuric acid 6 A 422 234 -187 1.800
H2SO4 Sulfuric acid 8 A 224 138 -86 1.621
H2SO4 Sulfuric acid 10 B 1452 1159 -294 1.254
MgH2 magnesium dihydride 2 Σu 1572 2093 521 0.751
HNO3 Nitric acid 8 A" 762 497 -265 1.532
HNO3 Nitric acid 6 A' 647 468 -179 1.381
HNO3 Nitric acid 7 A' 579 381 -198 1.518
SOCl2 thionyl chloride 4 A' 194 121 -73 1.601
SOCl2 thionyl chloride 3 A' 344 268 -76 1.282
SOCl2 thionyl chloride 1 A' 1251 1023 -228 1.223
SOCl2 thionyl chloride 6 A" 284 225 -59 1.259
PCl3 Phosphorus trichloride 4 E 198 157 -41 1.263
H2O2 Hydrogen peroxide 4 A 371 143 -228 2.600
H2O Water 1 A1 3657 3238 -419 1.129
O2+ diatomic oxygen cation 1 Σg 1906 1588 -318 1.200
HN3 hydrogen azide 5 A' 534 374 -161 1.430
HN3 hydrogen azide 6 A" 607 422 -185 1.438
NF3 Nitrogen trifluoride 2 A1 647 527 -120 1.227
NF3 Nitrogen trifluoride 4 E 492 383 -109 1.285
PF3 Phosphorus trifluoride 4 E 344 276 -68 1.247
PF3 Phosphorus trifluoride 2 A1 487 368 -119 1.322
SiF4 Silicon tetrafluoride 1 A1 800 616 -184 1.300
SiF4 Silicon tetrafluoride 4 T2 389 278 -111 1.401
SiF4 Silicon tetrafluoride 2 E 268 194 -74 1.379
AlF3 Aluminum trifluoride 2 A2" 297 206 -91 1.445
AlF3 Aluminum trifluoride 4 E' 263 202 -61 1.300
AsF5 Arsenic pentafluoride 1 A1' 734 563 -171 1.304
AsF5 Arsenic pentafluoride 3 A2" 787 651 -136 1.209
AsF5 Arsenic pentafluoride 7 E' 123 56 -67 2.205
AsF5 Arsenic pentafluoride 2 A1' 644 520 -124 1.240
AsF5 Arsenic pentafluoride 5 E' 811 619 -192 1.311
AsF5 Arsenic pentafluoride 6 E' 372 260 -112 1.431
AsF5 Arsenic pentafluoride 4 A2" 400 297 -103 1.345
AsF5 Arsenic pentafluoride 8 E" 386 281 -105 1.375
HSO3F Fluorosulfonic acid 6 A 823 582 -241 1.414
HSO3F Fluorosulfonic acid 8 A 551 255 -296 2.161
HSO3F Fluorosulfonic acid 2 A 1486 1134 -352 1.310
HSO3F Fluorosulfonic acid 3 A 1243 925 -318 1.344
HSO3F Fluorosulfonic acid 5 A 896 628 -268 1.428
HSO3F Fluorosulfonic acid 10 A 409 230 -179 1.780
HSO3F Fluorosulfonic acid 4 A 1150 819 -331 1.405
HSO3F Fluorosulfonic acid 9 A 518 244 -274 2.121
HSO3F Fluorosulfonic acid 11 A 390 175 -215 2.229
HSO3F Fluorosulfonic acid 7 A 562 259 -303 2.166
HSO3F Fluorosulfonic acid 12 A 266 164 -102 1.622
FNO Nitrosyl fluoride 1 A' 1844 1463 -381 1.260
FNO3 Fluorine nitrate 7 A' 303 214 -89 1.417
FNO3 Fluorine nitrate 9 A" 152 123 -29 1.233
FNO3 Fluorine nitrate 8 A" 709 460 -249 1.543
ClF3 Chlorine trifluoride 2 A1 529 439 -90 1.204
ClF3 Chlorine trifluoride 4 B1 328 185 -143 1.774
ClF3 Chlorine trifluoride 1 A1 752 558 -194 1.347
ClF3 Chlorine trifluoride 6 B2 442 302 -140 1.463
ClF3 Chlorine trifluoride 3 A1 328 258 -70 1.270
SO2Cl2 Sulfuryl chloride 1 A1 1205 846 -359 1.424
SO2Cl2 Sulfuryl chloride 3 A1 408 238 -170 1.711
SO2Cl2 Sulfuryl chloride 6 B1 586 400 -186 1.463
SO2Cl2 Sulfuryl chloride 9 B2 362 209 -153 1.735
SO2Cl2 Sulfuryl chloride 2 A1 577 390 -187 1.479
SO2Cl2 Sulfuryl chloride 4 A1 218 108 -110 2.026
SO2Cl2 Sulfuryl chloride 5 A2 282 156 -126 1.813
SO2Cl2 Sulfuryl chloride 7 B1 388 211 -177 1.836
SO2Cl2 Sulfuryl chloride 8 B2 1434 948 -486 1.513
NH2OH hydroxylamine 9 A" 386 202 -184 1.910
ZnCN Zinc monocyanide 2 Σ 418 696 278 0.601
ZnCN Zinc monocyanide 3 Π 212 153 -59 1.387
N2O Nitrous oxide 3 Π 589 390 -199 1.511
NCl3 nitrogen trichloride 4 E 257 209 -48 1.229
Cl3PO Phosphoryl chloride 3 A1 266 187 -79 1.426
Cl3PO Phosphoryl chloride 4 E 590 484 -106 1.218
Cl3PO Phosphoryl chloride 1 A1 1322 1073 -249 1.232
Cl3PO Phosphoryl chloride 5 E 333 224 -109 1.487
Cl3PO Phosphoryl chloride 6 E 187 128 -59 1.457
SiCl4 Silane, tetrachloro- 4 T2 221 182 -39 1.212
SiCl4 Silane, tetrachloro- 2 E 150 122 -28 1.227
PCl5 Phosphorus pentachloride 7 E' 100 58 -42 1.732
PCl5 Phosphorus pentachloride 2 A1' 370 299 -71 1.237
PCl5 Phosphorus pentachloride 4 A2" 299 233 -66 1.282
PCl5 Phosphorus pentachloride 6 E' 273 209 -64 1.306
PCl5 Phosphorus pentachloride 8 E" 261 199 -62 1.314
O3 Ozone 2 A1 705 553 -152 1.275
H3BO3 Boric acid 4 A" 666 539 -127 1.236
H3BO3 Boric acid 9 E' 432 357 -75 1.211
OClO Chlorine dioxide 2 A1 448 223 -225 2.010
OClO Chlorine dioxide 3 B2 1110 591 -519 1.877
OClO Chlorine dioxide 1 A1 946 659 -286 1.434
NO+ nitric oxide cation 1 Σ 2377 1792 -585 1.326
NO2 Nitrogen dioxide 2 A1 750 558 -192 1.343
N2O4 Dinitrogen tetroxide 6 B1u 755 550 -206 1.374
N2O4 Dinitrogen tetroxide 12 B3u 425 276 -149 1.542
N2O4 Dinitrogen tetroxide 2 Ag 807 659 -148 1.225
N2O4 Dinitrogen tetroxide 7 B2g 657 453 -204 1.452
N2O4 Dinitrogen tetroxide 9 B2u 265 83 -182 3.181
N2O4 Dinitrogen tetroxide 4 Au 82 66 -16 1.248
N2O4 Dinitrogen tetroxide 11 B3g 480 361 -119 1.329
N2O3 Dinitrogen trioxide 4 A' 773 641 -132 1.206
N2O3 Dinitrogen trioxide 7 A' 205 159 -46 1.286
N2O3 Dinitrogen trioxide 9 A" 63 112 49 0.561
NaK Sodium Potassium 1 Σ 124 242 118 0.514
Li2O dilithium oxide 3 Πu 112 168 57 0.664
C3 carbon trimer 3 Πu 63 144 80 0.441
CaOH Calcium monohydroxide 2 Σ 353 581 228 0.607
CaOH Calcium monohydroxide 3 Π 609 -265 -874 -2.301
C4 Carbon tetramer 4 Πg 323 169 -154 1.911
C4 Carbon tetramer 5 Πu 160 113 -47 1.411
ClNO2 Nitryl chloride 4 B1 652 461 -191 1.414
ClNO2 Nitryl chloride 6 B2 408 312 -96 1.306
ClNO2 Nitryl chloride 2 A1 793 629 -163 1.260
H2S2 HSSH 4 A 417 300 -117 1.390
F3PO Phosphoryl fluoride 6 E 336 196 -140 1.712
F3PO Phosphoryl fluoride 1 A1 1417 1056 -361 1.342
F3PO Phosphoryl fluoride 3 A1 472 303 -169 1.557
F3PO Phosphoryl fluoride 4 E 991 765 -226 1.296
F3PO Phosphoryl fluoride 5 E 482 263 -219 1.831
F3PO Phosphoryl fluoride 2 A1 873 637 -236 1.371
CuH Copper monohydride 1 Σ 1941 1542 -399 1.259
GeH3 germyl radical 2 A1 663 549 -114 1.207
NH2- amino anion 3 B2 3190 2647 -543 1.205
NH2- amino anion 1 A1 3122 2545 -577 1.227
N2F2 Dinitrogen difluoride, (E)- 6 Bu 423 321 -102 1.319
N2F2 Dinitrogen difluoride, (E)- 1 Ag 1523 1178 -345 1.292
N2F2 Dinitrogen difluoride, (E)- 4 Au 364 287 -77 1.268
AlF2Cl Aluminum chloride difluoride 4 B1 260 200 -60 1.301
AlF2Cl Aluminum chloride difluoride 3 A1 250 198 -52 1.262
CaF Calcuium monofluoride 1 Σ 581 419 -163 1.388
SO+ sulfur monoxide cation 1 Σ 1360 1098 -262 1.238
DF Hydrofluoric acid-d 1 Σ 2998 2519 -480 1.190
ClONO2 Chlorine nitrate 6 A' 434 348 -86 1.246
ClONO2 Chlorine nitrate 8 A" 711 470 -241 1.512
ClONO2 Chlorine nitrate 7 A' 273 190 -83 1.439
ClONO2 Chlorine nitrate 9 A" 124 91 -33 1.366
FO2 Dioxygen monofluoride 1 A' 1487 1189 -298 1.251
FO2 Dioxygen monofluoride 2 A' 579 990 410 0.585
ClOO chloroperoxy radical 3 A' 201 321 120 0.627
PN+ phosphorus nitride cation 1 Σ 1200 959 -241 1.251
AlH4- Aluminum tetrahydride anion 3 T2 1628 2043 415 0.797
SSO Disulfur monoxide 1 A' 1166 913 -253 1.277
SSO Disulfur monoxide 3 A' 380 295 -85 1.289
OBrO OBrO 2 A1 312 206 -106 1.514
OBrO OBrO 3 B2 849 565 -283 1.502
OBrO OBrO 1 A1 799 620 -179 1.289
NCO isocyanato radical 1 Σ 1921 1516 -405 1.267
NCO isocyanato radical 3 Π 535 408 -127 1.312
GeH2 germylene 1 A1 1856 1096 -760 1.694
Na2 Sodium diatomic 1 Σg 159 429 270 0.371
H3+ hydrogen trimer cation 2 E' 2521 1785 -736 1.412
ZnCH2 Zinc methylene 3 A1 514 758 245 0.677
ZnCH2 Zinc methylene 6 B2 544 306 -238 1.776
ZnCH2 Zinc methylene 4 B1 525 1071 547 0.490