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XIII.F.2. (III.B.7.b.) (IV.C.7.) (XVIII.B.2.)

Bad vibrational frequency predictions

Calculated frequencies that differ from experiment by more than 400 cm-1 or have a ratio with experiment outside of 0.7 to 1.2 are listed

Calculated vibrational frequencies ("theory" in table) are calculated at PM3
Calculated values were scaled by 0.974.

Species Name mode Symmetry Experiment Theory difference ratio
CH3ONO Methyl nitrite 15 A" 186 124 -62 1.501
C5H8 1,3-Pentadiene, (Z)- 22 A' 144 288 144 0.501
C5H8 1,3-Pentadiene, (Z)- 31 A" 456 337 -119 1.352
C5H10S 2H-Thiopyran, tetrahydro- 23 A' 194 141 -53 1.375
C5H10S 2H-Thiopyran, tetrahydro- 42 A" 242 192 -50 1.262
CH3OCH2CN Methoxyacetonitrile 15 A' 243 192 -51 1.269
C5H8 1,3-Pentadiene, (E)- 31 A" 361 218 -143 1.654
CH2+ methylene cation 2 A1 968 773 -196 1.253
C4H9N Cyclobutylamine 36 A" 240 126 -114 1.904
SF6 Sulfur Hexafluoride 6 T2u 347 202 -145 1.716
ClFO3 Perchloryl fluoride 3 A1 549 345 -204 1.589
ClFO3 Perchloryl fluoride 5 E 589 407 -182 1.448
ClFO3 Perchloryl fluoride 6 E 405 283 -122 1.433
H2SO4 Sulfuric acid 7 A 379 242 -137 1.565
H2SO4 Sulfuric acid 11 B 1157 908 -249 1.275
H2SO4 Sulfuric acid 13 B 558 403 -155 1.385
SOCl2 thionyl chloride 4 A' 194 144 -50 1.349
AlF3 Aluminum trifluoride 2 A2" 297 165 -132 1.802
SiCl4 Silane, tetrachloro- 3 T2 621 377 -244 1.646
P2 Phosphorus diatomic 1 Σg 781 541 -240 1.443
F3PO Phosphoryl fluoride 6 E 336 207 -129 1.620
AlF2Cl Aluminum chloride difluoride 4 B1 260 174 -86 1.494
PH- phosphorus monohydride anion 1 Σ 2230 1602 -628 1.392
AlH+ aluminum monohydride cation 1 Σ 1620 947 -673 1.711
Si2H6 disilane 9 Eg 625 517 -108 1.209
C2H3 vinyl 7 A' 674 462 -212 1.457
SO2 Sulfur dioxide 3 B2 1362 873 -489 1.561
AlCl3 Aluminum trichloride 4 E' 150 113 -37 1.327
SiO2 silicon dioxide 2 Σu 1416 1094 -323 1.295
O2 Oxygen diatomic 1 Σg 1580 2047 467 0.772
HSO3F Fluorosulfonic acid 6 A 823 626 -197 1.315
HSO3F Fluorosulfonic acid 8 A 551 375 -176 1.470
FNO3 Fluorine nitrate 5 A' 633 517 -116 1.226
FNO3 Fluorine nitrate 7 A' 303 212 -91 1.427
FNO3 Fluorine nitrate 9 A" 152 80 -72 1.903
P4 Phosphorus tetramer 2 E 361 298 -63 1.212
AlFCl2 Aluminum dichloride fluoride 2 A1 450 307 -143 1.464
PH+ phosphorus monohydride cation 1 Σ 2300 1719 -581 1.338
CSe Carbon monoselenide 1 Σ 1035 667 -368 1.553
ClOO chloroperoxy radical 2 A' 414 745 331 0.556
Al2 Aluminum diatomic 1 Σg 286 458 172 0.624
CH2SiH2 silaethylene 2 A1 2219 1843 -376 1.204
CH2SiH2 silaethylene 10 B2 2239 1837 -402 1.219
CH3COOH Acetic acid 11 A' 657 454 -203 1.446
CH3COCH3 Acetone 12 A2 77 56 -21 1.386
C2H6O2S Dimethyl sulfone 20 B1 262 25 -237 10.609
CH3CCl3 Ethane, 1,1,1-trichloro- 6 A2 214 137 -77 1.567
CF2Cl2 difluorodichloromethane 6 B1 902 702 -200 1.285
C5H8 1,3-Butadiene, 2-methyl- 22 A' 196 304 108 0.645
C6H5NO2 Nitrobenzene 15 A2 838 21 -817 39.145
C6H5NO2 Nitrobenzene 22 B1 675 149 -526 4.516
C6H5NO2 Nitrobenzene 25 B2 3080 1841 -1239 1.673
C6H5NO2 Nitrobenzene 32 B2 1162 597 -565 1.945
C6H5CHO benzaldehyde 36 A" 111 56 -55 1.994
CH2CHCHCH2 1,3-Butadiene 13 Au 162 75 -87 2.169
CH3OCHO methyl formate 11 A' 767 632 -135 1.213
NH2CN cyanamide 5 A' 408 1014 606 0.403
CH3PH2 Methyl phosphine 3 A' 2297 1538 -759 1.493
CH3PH2 Methyl phosphine 15 A" 207 136 -71 1.521
SO2Cl2 Sulfuryl chloride 1 A1 1205 749 -456 1.609
SO2Cl2 Sulfuryl chloride 9 B2 362 297 -65 1.220
SiHCl3 Trichlorosilane 4 E 811 658 -153 1.232
PCl5 Phosphorus pentachloride 7 E' 100 68 -32 1.461
C3 carbon trimer 3 Πu 63 385 322 0.165
PO2 Phosphorus dioxide 3 B2 1328 1021 -307 1.300
PO2 Phosphorus dioxide 2 A1 397 318 -79 1.249
C4 Carbon tetramer 4 Πg 323 488 165 0.662
C4 Carbon tetramer 5 Πu 160 269 109 0.595
SiCl2 Dichlorosilylene 3 B2 509 361 -149 1.412
PH2 Phosphino radical 2 A1 1102 911 -191 1.209
PH phosphorus monohydride 1 Σ 2364 1567 -797 1.509
HNO Nitrosyl hydride 1 A' 2684 3351 667 0.801
MgH magnesium monohydride 1 Σ 1493 2012 519 0.742
Mg2 Magnesium diatomic 1 Σg 51 455 404 0.112
ZnCH3 Zinc monomethyl 6 E 315 518 203 0.608
C2H4O Ethylene oxide 7 A2 1300 1041 -259 1.249
C3H4N2 1H-Imidazole 20 A" 621 512 -109 1.213
C5H12 Propane, 2,2-dimethyl- 4 A2 198 139 -59 1.422
CF2O Carbonic difluoride 3 A1 584 440 -144 1.326
C3H6O Oxetane 23 B2 1228 987 -241 1.244
CH3F Methyl fluoride 6 E 1182 982 -200 1.204
C3H8O2S (Methylsulphonyl)ethane 28 ?a 519 418 -101 1.243
CH3NO3 Methyl nitrate 16 A" 758 622 -136 1.219
CH3NO3 Methyl nitrate 11 A' 578 319 -259 1.813
CH3SSCH3 Disulfide, dimethyl 11 A 240 197 -43 1.216
C2H5NO3 Nitric acid, ethyl ester 27 A" 112 46 -66 2.454
C2H5NO3 Nitric acid, ethyl ester 13 A' 851 598 -253 1.422
C2H5NO3 Nitric acid, ethyl ester 15 A' 566 416 -150 1.360
C4N2 2-Butynedinitrile 9 Πu 107 170 63 0.629
CH2 Methylene 2 A1 963 697 -267 1.383
SiH2Cl2 dichlorosilane 4 A1 188 141 -47 1.334
SiH2Cl2 dichlorosilane 7 B1 602 475 -127 1.267
H2CO+ formaldehyde cation 6 B2 824 600 -224 1.373
C3H4O2 β–Propiolactone 13 A' 513 404 -109 1.269
C3H8 Propane 20 B1 268 195 -73 1.373
CH3CHClCH3 Propane, 2-chloro- 27 A" 276 148 -128 1.865
CH3CHClCH3 Propane, 2-chloro- 15 A' 253 164 -89 1.545
CH3COCl Acetyl Chloride 15 A" 166 72 -94 2.293
CHF2Cl difluorochloromethane 4 A' 812 658 -154 1.234
CH2ClCHClCH3 Propane, 1,2-dichloro- 26 A 203 164 -39 1.235
C3H2N2 Malononitrile 7 A2 1220 996 -224 1.225
C4H9N Pyrrolidine 36 A" 65 119 54 0.548
C4H9N Pyrrolidine 19 A' 299 143 -156 2.093
C4H8O2 1,4-Dioxane 19 Au 288 181 -107 1.593
C4H8O2 1,4-Dioxane 10 Ag 424 332 -92 1.279
C4H8O2 1,4-Dioxane 5 Ag 1305 1087 -218 1.201
C2Cl4 Tetrachloroethylene 4 Au 110 86 -24 1.281
C3H4N2 1H-Pyrazole 19 A" 674 553 -121 1.219
SO3 Sulfur trioxide 1 A1' 1065 753 -312 1.413
C2Cl2+ dichloroacetylene cation 4 Πg 318 528 211 0.601
HN3 hydrogen azide 5 A' 534 425 -109 1.256
H2Se+ Hydrogen selenide cation 1 A1 2267 1692 -575 1.340
SiF4 Silicon tetrafluoride 4 T2 389 303 -86 1.282
PH3 Phosphine 3 E 2328 1564 -764 1.488
SiHCl3 Trichlorosilane 1 A1 2261 1792 -469 1.262
SCl2 Sulfur dichloride 2 A1 208 165 -43 1.264
LiO lithium oxide 1 Σ 815 275 -540 2.963
H2S2 HSSH 1 A 2556 1581 -975 1.617
H2S2 HSSH 5 B 2559 1583 -975 1.616
NH+ imidogen cation 1 Σ 2922 3441 519 0.849
SiCl3 trichlorosilyl radical 3 E 582 388 -194 1.500
SSO Disulfur monoxide 1 A' 1166 816 -350 1.429
SSO Disulfur monoxide 3 A' 380 298 -82 1.276
HCOOH Formic acid 7 A' 625 475 -150 1.315
CH3CH2NH2 Ethylamine 24 A" 218 170 -48 1.281
N(CH3)3 Trimethylamine 22 E 281 155 -126 1.810
C3H6O 2-Propen-1-ol 23 A 277 152 -125 1.823
C6H5Cl chlorobenzene 20 B1 198 158 -40 1.252
C5H11N Piperidine 45 A" 254 195 -59 1.305
CH3NHCH3 Dimethylamine 13 A' 230 179 -51 1.285
C3H3NO Oxazole 18 A" 607 493 -114 1.231
C2H3N3 1H-1,2,4-Triazole 17 A" 660 535 -125 1.233
Zn(CH3)2 dimethyl zinc 11 E' 134 96 -38 1.395
C6H10 1,5-Hexadiene 14 Ag 351 290 -61 1.211
CH3ONO Methyl nitrite 8 A' 838 644 -194 1.301
C2H Ethynyl radical 3 Π 372 672 300 0.553
SF6 Sulfur Hexafluoride 1 A1g 774 627 -146 1.233
HCO Formyl radical 1 A' 2434 2847 412 0.855
HCO Formyl radical 3 A' 1081 899 -182 1.202
OH+ hydoxyl cation 1 Σ 3113 3574 461 0.871
CHOCHCHCH3 2-Butenal 25 A" 295 228 -67 1.295
CHOCHCHCH3 2-Butenal 27 A" 122 68 -54 1.794
SeO2 Selenium dioxide 2 A1 373 278 -94 1.338
SeO2 Selenium dioxide 3 B2 966 672 -294 1.437
ClFO3 Perchloryl fluoride 4 E 1315 1014 -301 1.297
NH3 Ammonia 2 A1 950 1362 412 0.698
H2SO4 Sulfuric acid 3 A 1136 885 -251 1.284
H2SO4 Sulfuric acid 5 A 548 405 -143 1.353
H2SO4 Sulfuric acid 14 B 506 330 -176 1.534
HNO3 Nitric acid 6 A' 647 488 -159 1.326
H2O+ water cation 1 A1 3213 3669 456 0.876
H2Se Hydrogen selenide 3 B2 2358 1569 -789 1.503
S2Cl2 Disulfur dichloride 6 B 244 185 -59 1.321
O3 Ozone 1 A1 1110 1551 441 0.716
PS+ phosphorus monosulfide cation 1 Σ 845 687 -157 1.229
SeO Selenium monoxide 1 Σ 915 683 -232 1.339
F3PO Phosphoryl fluoride 1 A1 1417 1002 -415 1.414
F3PO Phosphoryl fluoride 3 A1 472 310 -162 1.523
F3PO Phosphoryl fluoride 4 E 991 780 -211 1.271
F3PO Phosphoryl fluoride 5 E 482 324 -158 1.488
D2S Hydrogen sulfide-d2 1 A1 1896 1269 -627 1.494
NH2+ Amino cation 1 A1 3044 3491 447 0.872
AlF2Cl Aluminum chloride difluoride 2 A1 500 372 -128 1.345
AlH2 aluminum dihydride 2 A1 760 1101 341 0.690
AlH2 aluminum dihydride 3 B2 1807 1261 -545 1.432
C4H6O Cyclobutanone 20 B1 63 168 105 0.375
LiOH lithium hydroxide 2 Σ 871 273 -597 3.184
Si2H6 disilane 6 A2u 844 686 -157 1.229
OCSe Carbonyl selenide 2 Σ 644 435 -209 1.479
C3H5 Allyl radical 12 B1 518 431 -87 1.201
CF3 Trifluoromethyl radical 2 A1 701 572 -129 1.226
CF3 Trifluoromethyl radical 4 E 509 419 -90 1.215
C6H8 1,3,5-Hexatriene, (Z)- 11 A1 1136 901 -235 1.261
C6H8 1,3,5-Hexatriene, (Z)- 19 A2 264 125 -139 2.114
C6H8 1,3,5-Hexatriene, (Z)- 36 B2 243 383 140 0.634
H2CO+ formaldehyde cation 3 A1 1210 887 -323 1.365
CH3CH2Cl Ethyl chloride 18 A" 251 160 -91 1.566
CH3CH2SH ethanethiol 4 A' 2580 1675 -905 1.540
HNCO Isocyanic acid 5 A' 577 458 -119 1.260
CHOCH(CH3)CH3 Propanal, 2-methyl- 33 A" 75 55 -20 1.355
CHOCH(CH3)CH3 Propanal, 2-methyl- 19 A' 212 171 -41 1.239
CH2ClCHClCH3 Propane, 1,2-dichloro- 25 A 250 199 -51 1.254
CH3COOCH3 methyl acetate 27 A" 110 35 -75 3.139
CH3COOCH3 methyl acetate 22 A" 1187 988 -199 1.201
C4H5N Pyrrole 15 B1 621 508 -113 1.222
C4H4S Thiophene 14 B1 452 373 -79 1.210
C5H8 Cyclopentene 18 A' 254 111 -143 2.291
C3H3NO Isoxazole 17 A" 632 526 -106 1.202
C4H4N2 Pyrazine 21 B3g 1346 1103 -243 1.220
C2H5F fluoroethane 18 A" 243 167 -76 1.459
CF2O Carbonic difluoride 4 B1 774 622 -152 1.245
C3H6O Oxetane 18 B1 90 230 140 0.390
C3H6O Oxetane 11 A2 1185 931 -254 1.272
C5H8 1,4-Pentadiene 16 A 137 288 151 0.476
C3H8O2S (Methylsulphonyl)ethane 24 ?a 1060 768 -292 1.381
CH3NO3 Methyl nitrate 9 A' 854 593 -261 1.440
C5H6S Thiophene, 3-methyl- 28 A" 464 379 -85 1.223
CH3SSCH3 Disulfide, dimethyl 12 A 134 95 -39 1.405
C2H5NO3 Nitric acid, ethyl ester 25 A" 203 160 -43 1.268
C2H5NO3 Nitric acid, ethyl ester 16 A' 378 275 -103 1.376
C4H6 Cyclobutene 10 A2 1276 1053 -223 1.212
SiH2Cl2 dichlorosilane 8 B2 876 714 -162 1.227
SO2 Sulfur dioxide 2 A1 518 399 -119 1.298
SeS- selenium monosulfide anion 1 Σ 469 226 -243 2.073
AlCl3 Aluminum trichloride 3 E' 595 378 -217 1.574
MgH2 magnesium dihydride 3 Πu 440 313 -127 1.405
H2S Hydrogen sulfide 1 A1 2615 1770 -845 1.477
HSO3F Fluorosulfonic acid 2 A 1486 1066 -420 1.394
HSO3F Fluorosulfonic acid 4 A 1150 876 -274 1.312
HSO3F Fluorosulfonic acid 9 A 518 344 -174 1.507
HSO3F Fluorosulfonic acid 11 A 390 226 -164 1.729
FNO3 Fluorine nitrate 4 A' 804 659 -145 1.220
NO2 Nitrogen dioxide 2 A1 750 555 -195 1.351
NO2 Nitrogen dioxide 3 B2 1618 2055 437 0.787
C5H5- cylopentadienyl anion 2 A1' 983 1404 421 0.700
AlFCl2 Aluminum dichloride fluoride 3 A1 150 115 -35 1.304
AlFCl2 Aluminum dichloride fluoride 6 B2 200 156 -44 1.284
ClOO chloroperoxy radical 3 A' 201 420 218 0.480
CH3COOH Acetic acid 18 A" 93 34 -59 2.753
C2H6O2S Dimethyl sulfone 8 A1 496 387 -109 1.281
C2H6O2S Dimethyl sulfone 18 B1 986 760 -226 1.297
CH3CHO Acetaldehyde 15 A" 150 114 -36 1.314
CFCl3 Trichloromonofluoromethane 4 E 847 676 -171 1.253
CF4 Carbon tetrafluoride 2 E 435 354 -81 1.229
CHClCCl2 Trichloroethylene 9 A' 178 144 -34 1.233
C6H5NO2 Nitrobenzene 3 A1 3050 1564 -1486 1.950
C6H5NO2 Nitrobenzene 10 A1 1002 653 -349 1.534
C6H5NO2 Nitrobenzene 20 B1 791 597 -194 1.325
CH2CHCHO Acrolein 18 A" 157 75 -82 2.104
CH2C(CH3)CH3 1-Propene, 2-methyl- 15 A2 193 76 -117 2.539
C3O2 Carbon suboxide 7 Πu 61 227 166 0.269
SF6 Sulfur Hexafluoride 3 T1u 948 759 -188 1.248
SeO2 Selenium dioxide 1 A1 922 636 -286 1.451
H2SO4 Sulfuric acid 6 A 422 307 -115 1.375
H2SO4 Sulfuric acid 10 B 1452 1092 -360 1.329
HNO3 Nitric acid 7 A' 579 380 -199 1.522
H2S+ Hydrogen sulfide cation 1 A1 2496 1694 -802 1.473
S2Cl2 Disulfur dichloride 3 A 202 157 -45 1.284
SiCl4 Silane, tetrachloro- 1 A1 424 269 -155 1.578
SiCl4 Silane, tetrachloro- 2 E 150 102 -48 1.468
SiH3Cl chlorosilane 3 A1 551 374 -177 1.474
D2S Hydrogen sulfide-d2 3 B2 1999 1269 -730 1.576
AlF2Cl Aluminum chloride difluoride 6 B2 200 127 -73 1.573
Si2H6 disilane 2 A1g 909 755 -154 1.203
CF2 Difluoromethylene 3 B2 1114 1528 414 0.729
C6H8 1,3,5-Hexatriene, (Z)- 24 B1 358 54 -304 6.580
C5H12S Propane, 2-methyl-2-(methylthio)- 27 A' 226 187 -39 1.208
SiO2 silicon dioxide 3 Πu 273 192 -81 1.422
HF+ hydrogen fluoride cation 1 Σ 2913 3374 461 0.863
PCl3 Phosphorus trichloride 2 A1 252 186 -66 1.353
PCl3 Phosphorus trichloride 4 E 198 136 -62 1.456
AlH3 aluminum trihydride 4 E' 783 615 -169 1.274
HSO3F Fluorosulfonic acid 7 A 562 396 -166 1.419
HSO3F Fluorosulfonic acid 12 A 266 199 -67 1.334
FNO3 Fluorine nitrate 6 A' 455 340 -115 1.336
MgCl magnesium monochloride 1 Σ 462 877 415 0.527
C2H6O2S Dimethyl sulfone 6 A1 1013 713 -300 1.420
CCl2O Phosgene 5 B2 849 618 -231 1.374
CF2Cl2 difluorodichloromethane 4 A1 262 218 -44 1.201
CHClCCl2 Trichloroethylene 12 A" 215 179 -36 1.201
C6H5NO2 Nitrobenzene 11 A1 851 397 -454 2.143
C6H5NO2 Nitrobenzene 14 A2 975 342 -633 2.850
C6H5NO2 Nitrobenzene 18 B1 998 789 -209 1.265
C6H5NO2 Nitrobenzene 26 B2 3080 1727 -1353 1.783
C6H5NO2 Nitrobenzene 31 B2 1308 1087 -221 1.203
C6H5NO2 Nitrobenzene 33 B2 1069 520 -549 2.055
C6H5CHCH2 Styrene 40 A" 422 351 -71 1.203
C4H4N2 1,3-Diazine 20 B2 1356 1101 -255 1.231
C4H6O2 2,3-Butanedione 9 Ag 614 502 -112 1.224
C4H6O2 2,3-Butanedione 16 Au 48 -51 -99 -0.936
C4H6O2 2,3-Butanedione 21 Bg 240 96 -144 2.492
CH3PH2 Methyl phosphine 11 A" 2312 1583 -729 1.460
SO3 Sulfur trioxide 2 A2" 498 410 -88 1.214
SO3 Sulfur trioxide 3 E' 1391 1044 -347 1.332
SO3 Sulfur trioxide 4 E' 530 391 -139 1.355
PF5 Phosphorus pentafluoride 8 E" 520 364 -156 1.430
PF5 Phosphorus pentafluoride 4 A2" 575 399 -176 1.440
PF5 Phosphorus pentafluoride 5 E' 1024 846 -178 1.210
HN3 hydrogen azide 6 A" 607 446 -161 1.362
H2Se+ Hydrogen selenide cation 2 A1 1017 805 -212 1.263
PF3 Phosphorus trifluoride 4 E 344 245 -99 1.405
PF3 Phosphorus trifluoride 2 A1 487 326 -161 1.494
LiF lithium fluoride 1 Σ 911 163 -747 5.571
SO2Cl2 Sulfuryl chloride 4 A1 218 148 -70 1.475
SO2Cl2 Sulfuryl chloride 5 A2 282 227 -55 1.241
SO2Cl2 Sulfuryl chloride 8 B2 1434 981 -453 1.462
PH3 Phosphine 1 A1 2323 1507 -816 1.542
N2O Nitrous oxide 3 Π 589 477 -112 1.235
SiHCl3 Trichlorosilane 3 A1 254 177 -77 1.433
Cl3PO Phosphoryl chloride 6 E 187 128 -59 1.461
Cl3PO Phosphoryl chloride 1 A1 1322 1051 -271 1.258
Cl3PO Phosphoryl chloride 5 E 333 270 -63 1.234
PCl5 Phosphorus pentachloride 4 A2" 299 222 -77 1.344
PO2 Phosphorus dioxide 1 A1 1076 870 -206 1.237
Se2 Selenium diatomic 1 Σg 385 225 -160 1.711
H2S2 HSSH 4 A 417 345 -72 1.209
SiCl2 Dichlorosilylene 1 A1 522 377 -145 1.383
BeS beryllium sulfide 1 Σ 998 824 -174 1.211
PH2 Phosphino radical 1 A1 2310 1531 -779 1.509
HPO HPO 1 A' 2095 1507 -588 1.390
SH Mercapto radical 1 Σ 2696 1703 -993 1.583
ZnH2 Zinc hydride 3 Πu 633 465 -167 1.359
HNO Nitrosyl hydride 2 A' 1565 1999 434 0.783
MgF Magnesium monofluoride 1 Σ 712 1228 516 0.580
SiCl3 trichlorosilyl radical 1 A1 470 315 -155 1.492
ZnCH2 Zinc methylene 6 B2 544 429 -115 1.268
CH3SH Methanethiol 3 A' 2597 1676 -921 1.550
C2H5Br Ethyl bromide 18 A" 247 161 -86 1.535
N(CH3)3 Trimethylamine 11 A2 255 136 -119 1.876
C3H6O 2-Propen-1-ol 24 A 188 9 -179 20.440
C5H11N Piperidine 24 A' 404 315 -89 1.281
CO2 Carbon dioxide 3 Πu 667 494 -173 1.351
CH3NHCH3 Dimethylamine 24 A" 257 143 -114 1.792
C3H4N2 1H-Imidazole 19 A" 663 544 -119 1.218
C3H4N2 1H-Imidazole 21 A" 539 381 -158 1.415
C6H10 1,5-Hexadiene 29 Bg 264 101 -163 2.611
CH3ONO Methyl nitrite 3 A' 1613 2022 408 0.798
C2F2 difluoroacetylene 4 Πg 270 436 166 0.619
C3H6O Oxetane 16 B1 1142 938 -204 1.217
C5H8 1,4-Pentadiene 17 A 102 42 -60 2.407
C3H8O2S (Methylsulphonyl)ethane 29 ?a 491 402 -89 1.222
C5H8 1,2-Butadiene, 3-methyl- 23 B1 187 278 91 0.673
CH3NO3 Methyl nitrate 10 A' 657 485 -172 1.354
CH3NO3 Methyl nitrate 12 A' 340 250 -90 1.360
C2H5NO3 Nitric acid, ethyl ester 14 A' 702 583 -119 1.205
HCCCN Cyanoacetylene 7 Π 222 318 96 0.698
CH3C(SCH3)HCH3 Propane, 2-(methylthio)- 37 A 215 138 -77 1.561
C2H+ Ethynyl cation 3 Π 550 797 248 0.689
SiH2Cl2 dichlorosilane 3 A1 527 357 -170 1.476
C3H4O2 β–Propiolactone 21 A" 113 206 93 0.550
CH3NH2 methyl amine 14 A" 1195 894 -301 1.337
C3H8 Propane 14 A2 216 157 -59 1.375
HNCO Isocyanic acid 6 A" 656 463 -193 1.416
CH3CH(CH3)CH3 Isobutane 12 A2 198 152 -46 1.302
CH2ClCHClCH3 Propane, 1,2-dichloro- 27 A 108 68 -40 1.587
C5H12 Pentane 32 B1 215 179 -36 1.201
C5H12 Pentane 23 A2 131 80 -51 1.647
C3H4N2 1H-Pyrazole 20 A" 623 518 -105 1.203
CH2N4 1H-Tetrazole 15 A" 578 455 -123 1.271
C3H3N3 1,3,5-Triazine 4 A2' 1278 1048 -230 1.220
CH3CF3 Ethane, 1,1,1-trifluoro- 6 A2 225 140 -85 1.604
SO2 Sulfur dioxide 1 A1 1151 779 -372 1.477
AlCl3 Aluminum trichloride 1 A1' 375 269 -106 1.395
MgH2 magnesium dihydride 2 Σu 1572 2053 482 0.766
H2S Hydrogen sulfide 3 B2 2626 1765 -861 1.488
AlH3 aluminum trihydride 2 A2" 698 472 -226 1.478
HSO3F Fluorosulfonic acid 3 A 1243 938 -305 1.326
HSO3F Fluorosulfonic acid 5 A 896 744 -152 1.205
HSO3F Fluorosulfonic acid 10 A 409 259 -150 1.579
NO- nitric oxide anion 1 Σ 1363 1898 535 0.718
NS Mononitrogen monosulfide 1 Σ 1219 993 -225 1.227
AlFCl2 Aluminum dichloride fluoride 4 B1 220 173 -47 1.274
AlFCl2 Aluminum dichloride fluoride 5 B2 610 416 -194 1.467
N2F2 Dinitrogen difluoride, (E)- 6 Bu 423 346 -77 1.223
CH3COCH3 Acetone 17 B1 125 98 -28 1.283
C2H6O2S Dimethyl sulfone 17 B1 1269 971 -298 1.307
CF4 Carbon tetrafluoride 4 T2 631 506 -125 1.248
C6H5NO2 Nitrobenzene 2 A1 3080 1739 -1341 1.771
C6H5NO2 Nitrobenzene 9 A1 1021 815 -206 1.252
C6H5NO2 Nitrobenzene 19 B1 936 696 -240 1.345
C6H5NO2 Nitrobenzene 21 B1 704 408 -296 1.726
C6H5NO2 Nitrobenzene 29 B2 1460 1208 -252 1.209
C6H5NO2 Nitrobenzene 34 B2 613 233 -380 2.626
CH3OCHO methyl formate 17 A" 332 253 -79 1.313
CH2C(CH3)CH3 1-Propene, 2-methyl- 21 B1 196 110 -86 1.775
N2H4 Hydrazine 7 A 377 231 -146 1.631
C4H6O2 2,3-Butanedione 13 Au 1111 922 -189 1.204
CH3OCH2CN Methoxyacetonitrile 19 A" 1287 1025 -262 1.255
CH3OCH2CN Methoxyacetonitrile 24 A" 113 48 -65 2.371
SF6 Sulfur Hexafluoride 2 Eg 642 495 -147 1.297
SF6 Sulfur Hexafluoride 4 T1u 616 405 -211 1.521
SF6 Sulfur Hexafluoride 5 T2g 525 343 -182 1.529
CHOCHCHCH3 2-Butenal 26 A" 173 115 -58 1.499
H2SO4 Sulfuric acid 15 B 288 198 -89 1.451
SOCl2 thionyl chloride 1 A' 1251 746 -505 1.677
HNO2 Nitrous acid 6 A" 543 418 -125 1.298
H2Se Hydrogen selenide 1 A1 2345 1563 -782 1.500
AlF3 Aluminum trifluoride 4 E' 263 205 -58 1.285
SiCl4 Silane, tetrachloro- 4 T2 221 152 -69 1.452
O3 Ozone 3 B2 1042 1558 516 0.669
SiH3Cl chlorosilane 6 E 664 548 -116 1.212
F3PO Phosphoryl fluoride 2 A1 873 703 -170 1.241
AlF2Cl Aluminum chloride difluoride 3 A1 250 203 -47 1.233
SiCl Clorosilylidyne 1 Σ 536 427 -108 1.253
AlH2 aluminum dihydride 1 A1 1770 3949 2179 0.448
C4H6O Cyclobutanone 12 A2 1163 939 -224 1.238
LiOH lithium hydroxide 3 Π 257 30 -227 8.690
Si2H6 disilane 4 A1u 131 76 -55 1.731
C3H5 Allyl radical 9 A2 549 433 -116 1.268
PF5 Phosphorus pentafluoride 6 E' 533 384 -149 1.389
SF4 Sulfur tetrafluoride 4 A1 228 71 -157 3.222
SiHCl3 Trichlorosilane 2 A1 499 333 -166 1.501
SiHCl3 Trichlorosilane 5 E 600 370 -230 1.623
SiHCl3 Trichlorosilane 6 E 176 127 -49 1.389
Cl3PO Phosphoryl chloride 3 A1 266 190 -76 1.401
PCl5 Phosphorus pentachloride 8 E" 261 189 -72 1.381
PCl5 Phosphorus pentachloride 6 E' 273 204 -69 1.337
MgS magnesium sulfide 1 Σ 529 964 435 0.549
C4 Carbon tetramer 3 Σu 1549 2044 495 0.758
Si2 Silicon diatomic 1 Σg 511 412 -99 1.240
HPO HPO 2 A' 1188 959 -229 1.238
CH2ClCH2Cl Ethane, 1,2-dichloro- 10 Au 123 63 -60 1.967
C5H11N Piperidine 25 A' 246 200 -46 1.233
C3H3NO Oxazole 17 A" 647 535 -112 1.209
C2H3N3 1H-1,2,4-Triazole 16 A" 693 557 -136 1.245
C2H3N3 1H-1,2,4-Triazole 18 A" 640 392 -248 1.634
CH2NN diazomethane 8 B2 1110 912 -198 1.217
C3H6O Oxetane 10 A2 1283 1035 -248 1.239
HCNO fulminic acid 5 Π 224 488 263 0.460
C5H8 1,4-Pentadiene 31 B 721 567 -154 1.272
C5H8 1,4-Pentadiene 33 B 331 48 -283 6.910
CH3SSCH3 Disulfide, dimethyl 24 B 134 94 -40 1.418
CH3SSCH3 Disulfide, dimethyl 13 A 117 89 -28 1.315
C2H5NO3 Nitric acid, ethyl ester 24 A" 765 629 -136 1.217
C2H5NO3 Nitric acid, ethyl ester 26 A" 120 86 -34 1.401
C2H5NO3 Nitric acid, ethyl ester 17 A' 242 194 -48 1.248
C6H8 1,4-Cyclohexadiene 19 B1u 108 77 -31 1.401
C3H7N Cyclopropylamine 27 A" 254 109 -145 2.337
SiH2Cl2 dichlorosilane 1 A1 2224 1831 -393 1.215
SiH2Cl2 dichlorosilane 6 B1 2237 1815 -422 1.232
SiH2Cl2 dichlorosilane 9 B2 590 370 -220 1.593
H2CO Formaldehyde 6 B2 1249 1027 -222 1.216
C2H6 Ethane 4 A1u 289 218 -71 1.324
CH2F2 Methane, difluoro- 5 A2 1262 959 -303 1.316
CH2F2 Methane, difluoro- 7 B1 1178 922 -257 1.278
CS2 Carbon disulfide 2 Σu 1535 1276 -259 1.203
CH3SCH3 Dimethyl sulfide 15 B1 182 86 -96 2.117
C3H6 Cyclopropane 4 A1" 1126 936 -190 1.203
CHOCH(CH3)CH3 Propanal, 2-methyl- 32 A" 227 154 -73 1.470
CHCCH2CH3 1-Butyne 24 A" 213 156 -57 1.367
C4H5N Pyrrole 16 B1 475 338 -137 1.405
C4H4O Furan 14 B1 613 494 -119 1.240
C3H6O3 1,3,5-Trioxane 20 E 307 226 -81 1.358
C3H6O3 1,3,5-Trioxane 7 A1 476 362 -114 1.314
CH2CHCH3 Propene 21 A" 174 113 -61 1.536
C2Cl4 Tetrachloroethylene 9 B2u 176 127 -49 1.389
C3H4N2 1H-Pyrazole 21 A" 516 332 -184 1.553
C3H3NO Isoxazole 18 A" 595 484 -111 1.230
CF2O Carbonic difluoride 6 B2 626 437 -189 1.432