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IV.C.1. (XIII.D.1.)

Compare vibrational frequencies in CCCBDB for N2O3 (Dinitrogen trioxide)

B3PW91/6-31G(2df,p)

Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency diff Symmetry Frequency Comment
1 A' 1872 40 A' 1832  
2 A' 1729 77 A' 1652  
3 A' 1360 55 A' 1305  
4 A' 793 20 A' 773  
5 A' 664 37 A' 627  
6 A' 294 53 A' 241  
7 A' 219 14 A' 205  
8 A" 472 58 A" 414  
9 A" 143 80 A" 63  
The calculated vibrational frequencies were scaled by 0.9614

See section XIII.C.3 List or set vibrational scaling factors to change the scale factors used here.
See section III.B.3.c Calculate a vibrational scaling factor for a set of molecules to determine the least squares best scaling factor.
See section III.B.3.b List of vibrational scaling factors and their uncertainties for information on where the above scaling factor is from.