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IV.C.1. (XIII.D.1.)

Compare vibrational frequencies in CCCBDB for N2O3 (Dinitrogen trioxide)

B3PW91/6-31+G**

Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency diff Symmetry Frequency Comment
1 A' 1884 52 A' 1832  
2 A' 1707 55 A' 1652  
3 A' 1355 50 A' 1305  
4 A' 783 10 A' 773  
5 A' 649 22 A' 627  
6 A' 281 40 A' 241  
7 A' 214 9 A' 205  
8 A" 456 42 A" 414  
9 A" 131 68 A" 63  
The calculated vibrational frequencies were scaled by 0.9601

See section XIII.C.3 List or set vibrational scaling factors to change the scale factors used here.
See section III.B.3.c Calculate a vibrational scaling factor for a set of molecules to determine the least squares best scaling factor.
See section III.B.3.b List of vibrational scaling factors and their uncertainties for information on where the above scaling factor is from.