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IV.C.1. (XIII.D.1.)

Compare vibrational frequencies in CCCBDB for N2O3 (Dinitrogen trioxide)

B3PW91/cc-pVDZ

Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency diff Symmetry Frequency Comment
1 A' 1896 64 A' 1832  
2 A' 1744 92 A' 1652  
3 A' 1371 66 A' 1305  
4 A' 799 26 A' 773  
5 A' 661 34 A' 627  
6 A' 294 53 A' 241  
7 A' 216 11 A' 205  
8 A" 462 48 A" 414  
9 A" 148 85 A" 63  
The calculated vibrational frequencies were scaled by 0.965

See section XIII.C.3 List or set vibrational scaling factors to change the scale factors used here.
See section III.B.3.c Calculate a vibrational scaling factor for a set of molecules to determine the least squares best scaling factor.
See section III.B.3.b List of vibrational scaling factors and their uncertainties for information on where the above scaling factor is from.