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IV.C.1. (XIII.D.1.)

Compare vibrational frequencies in CCCBDB for CF2 (Difluoromethylene)

B1B95/STO-3G

Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency diff Symmetry Frequency Comment
1 A1 1171 -54 A1 1225  
2 A1 552 -115 A1 667  
3 B2 1137 23 B2 1114  
The calculated vibrational frequencies were scaled by 0.883

See section XIII.C.3 List or set vibrational scaling factors to change the scale factors used here.
See section III.B.3.c Calculate a vibrational scaling factor for a set of molecules to determine the least squares best scaling factor.
See section III.B.3.b List of vibrational scaling factors and their uncertainties for information on where the above scaling factor is from.