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IV.C.1. (XIII.D.1.)

Compare vibrational frequencies in CCCBDB for H2POH (Phosphinous acid)

MP4/6-31G*

Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency diff Symmetry Frequency Comment
1 A' 3604 -40 A' 3644  
2 A' 2316 12 A' 2305  
3 A' 1148 24 A' 1124  
4 A' 1115 40 A' 1075  
5 A' 891 -24 A' 915  
6 A' 760 -37 A' 797  
7 A" 2318 40 A" 2278  
8 A" 886 38 A" 848  
9 A" 252 -124 A" 375  
The calculated vibrational frequencies were scaled by 0.9548

See section XIII.C.3 List or set vibrational scaling factors to change the scale factors used here.
See section III.B.3.c Calculate a vibrational scaling factor for a set of molecules to determine the least squares best scaling factor.
See section III.B.3.b List of vibrational scaling factors and their uncertainties for information on where the above scaling factor is from.