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IV.C.1. (XIII.D.1.)

Compare vibrational frequencies in CCCBDB for SF4 (Sulfur tetrafluoride)

HSEh1PBE/6-31G*

Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency diff Symmetry Frequency Comment
1 A1 851 -40 A1 892  
2 A1 574 16 A1 558  
3 A1 478 -54 A1 532  
4 A1 185 -43 A1 228  
5 A2 427 15 A2 412  
6 B1 840 -25 B1 865 B1 B2 switched
7 B1 326 -27 B1 353 B1 B2 switched
8 B2 791 61 B2 730 B1 B2 switched
9 B2 486 11 B2 475 B1 B2 switched
The calculated vibrational frequencies were scaled by 0.951

See section XIII.C.3 List or set vibrational scaling factors to change the scale factors used here.
See section III.B.3.c Calculate a vibrational scaling factor for a set of molecules to determine the least squares best scaling factor.
See section III.B.3.b List of vibrational scaling factors and their uncertainties for information on where the above scaling factor is from.