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IV.C.1. (XIII.D.1.)

Compare vibrational frequencies in CCCBDB for SO2Cl2 (Sulfuryl chloride)

LSDA/3-21G

Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency diff Symmetry Frequency Comment
1 A1 958 -247 A1 1205  
2 A1 429 -148 A1 577  
3 A1 275 -133 A1 408  
4 A1 114 -104 A1 218  
5 A2 156 -126 A2 282  
6 B1 410 -176 B1 586  
7 B1 240 -148 B1 388  
8 B2 1149 -285 B2 1434  
9 B2 213 -149 B2 362  
The calculated vibrational frequencies were scaled by 0.9836

See section XIII.C.3 List or set vibrational scaling factors to change the scale factors used here.
See section III.B.3.c Calculate a vibrational scaling factor for a set of molecules to determine the least squares best scaling factor.
See section III.B.3.b List of vibrational scaling factors and their uncertainties for information on where the above scaling factor is from.