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Compare vibrational frequencies in CCCBDB for ZnCH3 (Zinc monomethyl)

B3PW91/6-31G(2df,p)

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A1 3036 2918           
2 A1 1166 1121   57 A1   1064  
3 A1 552 531   86 A1   445  
4 E 3133 3012           
5 E 1432 1377           
6 E 597 574   259 E   315 Tentative
The calculated vibrational frequencies were scaled by 0.9614

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.