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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CH5N3 (Guanidine)


Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.001060 -0.007065 -0.007065 -0.004881 -0.015171 -0.016093 -0.016658 -0.075307 -0.076054 -0.035458 -0.069056 -0.009871 -0.059159   -0.011443 -0.069276 -0.119234
MP3=FULL         -0.014572   -0.034631                    
Coupled Cluster CCSD(T)=FULL         -0.014561           -0.071849 -0.009092 -0.095151 -0.083150 -0.010641 -0.069743 -0.163064
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ