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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For PS- (phosphorus monosulfide anion)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.001041 -0.010971 -0.026128 -0.006503 -0.021357 -0.021357 -0.022747 -0.244285 -0.244285 -0.040646 -0.012962 -0.075894 -0.111220 -0.112277
MP3=FULL         -0.020054                  
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVQZ