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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For C16H10 (Pyrene)


Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.007514 -0.028267 -0.028267 -0.023345 -0.081228 -0.082862 -0.084924 -0.301571 -0.303067 -0.132878 -0.274722 -0.040991 -0.257216
MP3=FULL         -0.080156                
Coupled Cluster CCSD(T)=FULL         0.054466                
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) TZVP cc-pVDZ cc-pVTZ