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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For PO (Phosphorus monoxide)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(D+d)Z cc-pV(T+d)Z aug-cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ aug-cc-pCVTZ
Moller Plesset perturbation MP2=FULL -0.001219 -0.007615 -0.015182 -0.053859 -0.014172 -0.014172 -0.015309 -0.142630 -0.142630 -0.029491 -0.190373 -0.047023 -0.008997 -0.053677 -0.082327 -0.010609 -0.058167 -0.083718   -0.115353 -0.119775 -0.244575 -0.376112 -0.376577
MP3=FULL         -0.013493   -0.024797       -0.189446 -0.047056 -0.026123 -0.053096         -0.052998 -0.115098 -0.119726 -0.246642 -0.378616 -0.379090
MP4=FULL   -0.007241     -0.016916       -0.179477   -0.191248   -0.008334 -0.053685   -0.010046 -0.058467     -0.116553 -0.121055 -0.247179 -0.381122 -0.381566
B2PLYP=FULL -0.000395 -0.003276 -0.004657 -0.001436 -0.004290 -0.052064 -0.004635 -0.091023 -0.041292 -0.008893 -0.055393 -0.060704 -0.044883 -0.016029   -0.003247 -0.017330   -0.015947 -0.034101 -0.035374 -0.070051 -0.107764 -0.107908
Quadratic configuration interaction QCISD(T)=FULL         -0.013522           -0.190790   -0.008355 -0.053754   -0.010099 -0.058365   -0.053039 -0.116147 -0.120695 -0.246953 -0.380457 -0.380904
QCISD(TQ)=FULL         -0.013488   -0.014647       -0.190637   -0.008324 -0.053741 -0.083773 -0.010032 -0.058376              
Coupled Cluster CCSD=FULL         -0.013210         -0.028260 -0.188846 -0.046752 -0.008114 -0.052716 -0.082418 -0.009837 -0.057355 -0.083824 -0.052445 -0.114534 -0.119101 -0.245632 -0.377245 -0.377676
CCSD(T)=FULL         -0.013541           -0.190771     -0.053776 -0.083821   -0.058394 -0.085229   -0.116128 -0.120684   -0.380418 -0.380871
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(D+d)Z cc-pV(T+d)Z aug-cc-pV(T+d)Z cc-pCVDZ cc-pCVTZ aug-cc-pCVTZ