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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CH3CO+ (acetyl cation)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVQZ
Moller Plesset perturbation MP2=FULL -0.000953 -0.004995 -0.004995 -0.003617 -0.012407 -0.012957 -0.013443 -0.055735 -0.056180 -0.023847 -0.007165 -0.043628 -0.085751 -0.087547
MP3=FULL         0.044464   -0.015759              
Coupled Cluster CCSD(T)=FULL         -0.012163                  
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVQZ