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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For HCS+ (Thioformyl cation)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ aug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.001185 -0.006859 -0.014813 -0.004524 -0.015728 -0.015934 -0.016696 -0.138722 -0.138907 -0.028542 -0.009247 -0.049537 -0.054185
MP3=FULL         -0.014850   -0.017296            
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ aug-cc-pVTZ