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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For CH2Cl (chloromethyl radical)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(D+d)Z cc-pV(T+d)Z cc-pCVTZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000389 -0.005861 -0.013310 -0.003843 -0.014446 -0.014813 -0.015467 -0.067229 -0.067551 -0.027021 -0.116900 -0.044015 -0.008468 -0.048718 -0.090471 -0.009825 -0.053513 -0.092080 -0.060637 -0.119797 -0.352941 -0.010186 -0.055105
MP3=FULL         -0.013527   -0.014525       -0.114908 -0.043768 -0.007541 -0.047317             -0.351195 -0.009157 -0.053890
MP4=FULL   -0.005490     -0.013719       -0.068306   -0.116421   -0.007710 -0.048195   -0.009059 -0.053215       -0.353265 -0.009407 -0.054853
B2PLYP=FULL -0.000120 -0.001779 -0.004006 -0.001164 -0.004319 -0.004423 -0.004619 -0.019347 -0.019444 -0.008018 -0.033874 -0.012809 -0.002557 -0.014380   -0.002963 -0.015743       -0.100459 -0.003071 -0.016199
Quadratic configuration interaction QCISD(T)=FULL         -0.013678           -0.116158   -0.007673 -0.048043   -0.009002 -0.053041       -0.352857 -0.009351 -0.054675
Coupled Cluster CCSD=FULL         -0.013404         -0.024671 -0.114748 -0.043707 -0.007446 -0.047161 -0.089300 -0.008731 -0.052116 -0.090906     -0.350296 -0.009071 -0.053735
CCSD(T)=FULL         -0.013672           -0.116124 -0.044267 -0.007666 -0.048019 -0.090715 -0.008991 -0.053014   -0.057946   -0.352850 -0.009339 -0.054648
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pV(D+d)Z cc-pV(T+d)Z cc-pCVTZ daug-cc-pVDZ daug-cc-pVTZ