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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For HCO3- (bicarbonate anion)

Energies in Hartree
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ aug-cc-pVTZ
Moller Plesset perturbation MP2=FULL -0.000603 -0.007052 -0.007052 -0.004426 -0.012967 -0.013111 -0.013921 -0.075048 -0.075163 -0.030686 -0.008909 -0.053901 -0.061613
MP3=FULL             -0.053678            
Coupled Cluster CCSD(T)=FULL         4.195660                
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) cc-pVDZ cc-pVTZ aug-cc-pVTZ