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Energy differences between frozen core and all electrons correlated.
MP2, MP3, MP4, B2PLYP, CCSD, and CCSD(T)

For ZnCl2 (Zinc dichloride)

Energies in Hartree
Methods with standard basis sets
3-21G 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p)
Moller Plesset perturbation MP2=FULL -0.066333 -0.063966 -0.083752 -0.083752 -0.147668 -0.517909 -0.517909 -0.143941
MP3=FULL     -0.062522   -0.184692      
Coupled Cluster CCSD(T)=FULL     -0.072108          
3-21G 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p)