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II.B.3. (XII.A.3.)

List of experimental bond lengths for bond type rPCl

Bond lengths in Å.
Click on an entry for more experimental geometry data.
bond type Species Name Length Comment
rPCl Cl3PO Phosphoryl chloride 1.989
rPCl PCl phosphorus chloride 2.018 from B0
rPCl PCl5 Phosphorus pentachloride 2.020 equatorial
rPCl PCl3 Phosphorus trichloride 2.043
rPCl PCl5 Phosphorus pentachloride 2.214 axial
 
Average 2.057 ±0.090
Min 1.989
Max 2.214