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II.A.3. (XII.A.1.)

Listing of experimental geometry data for SF5Cl (sulfur chloropentafluoride)

Rotational Constants (cm-1)
See section I.F.4 to change rotational constant units
A B C
  0.06086  
Rotational Constants from 1974Hel/Hel(II/6)
Calculated rotational constants for SF5Cl (sulfur chloropentafluoride).

Point Group C4v

Internal coordinates (distances (r) in Å) (angles (a) in degrees) (dihedrals (d) in degrees)
Description Value Connectivity Reference Comment
Atom 1 Atom 2 Atom 3 Atom 4
rSCl 2.030 1 2 1976Hellwege(II/7)
rFS 1.576 1 3 1976Hellwege(II/7)
aFSF 88.4 3 1 7 1976Hellwege(II/7) axial F
aFSCl 91.6 2 1 3 1976Hellwege(II/7) by symmetry
picture of sulfur chloropentafluoride

Bond descriptions
Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond
Bond Type Count
S-Cl 1
F-S 5

Atom x (Å) y (Å) z (Å)
S1 0.0000 0.0000 -0.2403
Cl2 0.0000 0.0000 1.7897
F3 0.0000 1.5754 -0.2843
F4 1.5754 0.0000 -0.2843
F5 0.0000 -1.5754 -0.2843
F6 -1.5754 0.0000 -0.2843
F7 0.0000 0.0000 -1.8163

Atom - Atom Distances (Å)
  S1 Cl2 F3 F4 F5 F6 F7
S12.03001.57601.57601.57601.57601.5760
Cl22.03002.60452.60452.60452.60453.6060
F31.57602.60452.22793.15082.22792.1975
F41.57602.60452.22792.22793.15082.1975
F51.57602.60453.15082.22792.22792.1975
F61.57602.60452.22793.15082.22792.1975
F71.57603.60602.19752.19752.19752.1975

Calculated geometries for SF5Cl (sulfur chloropentafluoride).


References
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squib reference DOI
1974Hel/Hel(II/6) Hellwege, KH and AM Hellwege (eds.). Landolt-Bornstein: Group II: Volume 6 Molecular Constants from Microwave, Molecular Beam, and Electron Spin Resonance Spectroscopy Springer-Verlag. Berlin. 1974.  
1976Hellwege(II/7) Hellwege, KH and AM Hellwege (ed.). Landolt-Bornstein: Group II: Atomic and Molecular Physics Volume 7: Structure Data of Free Polyatomic Molecules. Springer-Verlag. Berlin. 1976.  

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