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Compare vibrational frequencies for two calculations for CH4- (Methane anion)


A = HF/6-31G*
B = MP2/6-31G*

scale factors=0.8985, 0.943
  symmetry   frequency (cm-1)   reduced mass (amu)   IR Intensity (km mol-1)   Raman Activity (Å4/u)
mode number A B   A B diff. ratio   A B diff. ratio   A B diff. ratio   A B diff. ratio
1 A1 A1   2150 2233 -83.2 0.963   1.008 1.008 0.000 1.000   0.00 0.00 0.00            
2 E E   1300 1290 10.0 1.008   1.008 1.008 0.000 1.000   0.00 0.00 0.00            
3 E E   1300 1290 10.0 1.008   1.008 1.008 0.000 1.000   0.00 0.00 0.00            
4 T2 T2   1524 2223 -698.8 0.686   1.294 1.155 0.139 1.121   6378.10 1487.61 4890.49 4.287          
5 T2 T2   1524 2223 -698.8 0.686   1.294 1.155 0.139 1.121   6378.10 1487.61 4890.49 4.287          
6 T2 T2   1524 2223 -698.8 0.686   1.294 1.155 0.139 1.121   6378.10 1487.61 4890.49 4.287          
7 T2 T2   107i 927 -1033.8 -0.115   1.017 1.124 -0.107 0.905   4873.77 0.85 4872.92 5763.676          
8 T2 T2   107i 927 -1033.8 -0.115   1.017 1.124 -0.107 0.905   4873.76 0.85 4872.92 5763.676          
9 T2 T2   107i 927 -1033.8 -0.115   1.017 1.124 -0.107 0.905   4873.77 0.85 4872.92 5763.679          
scaled by     0.8985 0.943
19 08 20 15 07

See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.