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Compare vibrational frequencies in CCCBDB for PCl5 (Phosphorus pentachloride)

HF/LANL2DZ

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A1' 328 296   -98 A1'   394  
2 A1' 274 247   -17 A1'   264  
3 A2" 428 385   -80 A2"   465  
4 A2" 254 229   -70 A2"   299  
5 E' 515 464   -128 E'   592  
6 E' 225 202   -71 E'   273  
7 E' 74 67   -33 E'   100  
8 E" 217 195   -87 E"   282  
The calculated vibrational frequencies were scaled by 0.8999

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.