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Compare vibrational frequencies in CCCBDB for C5H8 (Cyclopentene)

HSEh1PBE/6-31G*

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3241 3082   16 A'   3066  
2 A' 3145 2991   33 A'   2958  
3 A' 3104 2952   36 A'   2916  
4 A' 3084 2933   31 A'   2902  
5 A' 3041 2892   40 A'   2852  
6 A' 1722 1637   21 A'   1616  
7 A' 1534 1459   -8 A'   1467  
8 A' 1506 1433   -16 A'   1449  
9 A' 1354 1288   -14 A'   1302  
10 A' 1246 1185   -99 A'   1284  
11 A' 1140 1084   -129 A'   1213  
12 A' 1081 1028   -20 A'   1048  
13 A' 999 950   -14 A'   964  
14 A' 931 885   -77 A'   962  
15 A' 836 795   -109 A'   904  
16 A' 721 686   -6 A'   692  
17 A' 610 580   -23 A'   603  
18 A' 150 143   -111 A'   254  
19 A" 3216 3058   19 A"   3039  
20 A" 3096 2944   -23 A"   2967  
21 A" 3042 2893   -34 A"   2927  
22 A" 1514 1440   -27 A"   1467  
23 A" 1403 1334   -98 A"   1432  
24 A" 1344 1278   -78 A"   1356  
25 A" 1320 1255   -47 A"   1302  
26 A" 1247 1186   -111 A"   1297  
27 A" 1165 1107   -100 A"   1207  
28 A" 1064 1012   -101 A"   1113  
29 A" 976 928   -154 A"   1082  
30 A" 940 894   -43 A"   937  
31 A" 908 864   64 A"   800  
32 A" 785 747   45 A"   702  
33 A" 394 375   -12 A"   387  
The calculated vibrational frequencies were scaled by 0.951

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.