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Compare vibrational frequencies in CCCBDB for CH2OH (Hydroxymethyl radical)

PBEPBE/3-21G*

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A 3384 3227   -423 A   3650  
2 A 3203 3054           
3 A 3046 2905           
4 A 1470 1402   -57 A   1459  
5 A 1347 1285   -49 A   1334  
6 A 1119 1067   -109 A   1176  
7 A 1018 970   -78 A   1048  
8 A 570 544   62 A   482  
9 A 432 412   178 A   234  
The calculated vibrational frequencies were scaled by 0.9535

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.