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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

HF/3-21G*

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3394 3064   -73 A'   3137  
2 A' 3273 2954   746 A'   2208  
3 A' 2552 2304   683 A'   1621  
4 A' 1852 1671   215 A'   1456  
5 A' 1655 1494           
6 A' 1343 1212   -3 A'   1215  
7 A' 962 869           
8 A' 675 609           
9 A' 282 255           
10 A" 1262 1139   49 A"   1090  
11 A" 863 779           
12 A" 446 403           
The calculated vibrational frequencies were scaled by 0.9026

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.