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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

CCSD/6-31G(2df,p)

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3258 3080   -57 A'   3137  
2 A' 3140 2969   761 A'   2208  
3 A' 2343 2216   595 A'   1621  
4 A' 1723 1629   173 A'   1456  
5 A' 1519 1436           
6 A' 1250 1182   -33 A'   1215  
7 A' 946 895           
8 A' 640 605           
9 A' 256 242           
10 A" 1113 1053   -37 A"   1090  
11 A" 790 747           
12 A" 384 363           
The calculated vibrational frequencies were scaled by 0.9455

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.