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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

B3PW91/6-31G(2df,p)

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3202 3078   -59 A'   3137  
2 A' 3083 2964   756 A'   2208  
3 A' 2321 2231   610 A'   1621  
4 A' 1720 1654   198 A'   1456  
5 A' 1500 1442           
6 A' 1220 1173   -42 A'   1215  
7 A' 969 932           
8 A' 636 611           
9 A' 253 243           
10 A" 1090 1048   -42 A"   1090  
11 A" 786 755           
12 A" 387 372           
The calculated vibrational frequencies were scaled by 0.9614

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.