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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

MP2=FULL/6-31+G**

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3319 3117   -20 A'   3137  
2 A' 3181 2987   779 A'   2208  
3 A' 2180 2047   426 A'   1621  
4 A' 1691 1588   132 A'   1456  
5 A' 1533 1439           
6 A' 1252 1176   -39 A'   1215  
7 A' 946 889           
8 A' 609 572           
9 A' 243 229           
10 A" 1100 1033   -57 A"   1090  
11 A" 776 729           
12 A" 343 322           
The calculated vibrational frequencies were scaled by 0.9392

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.