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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

PBEPBE/6-31G**

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3137 3094   -43 A'   3137  
2 A' 3013 2972   764 A'   2208  
3 A' 2218 2188   567 A'   1621  
4 A' 1653 1630   174 A'   1456  
5 A' 1466 1446           
6 A' 1185 1169   -46 A'   1215  
7 A' 949 936           
8 A' 593 585           
9 A' 237 234           
10 A" 1032 1017   -73 A"   1090  
11 A" 753 743           
12 A" 344 340           
The calculated vibrational frequencies were scaled by 0.9863

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.