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Compare vibrational frequencies in CCCBDB for HClO4 (perchloric acid)

MP2/3-21G*

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3412 3246   -311 A'   3557  
2 A' 1355 1289   -18 A'   1307  
3 A' 1188 1130   -50 A'   1180  
4 A' 1074 1022   -16 A'   1038  
5 A' 706 672   -39 A'   711  
6 A' 555 528   -41 A'   569  
7 A' 524 499   -49 A'   548  
8 A' 389 370   -35 A'   405  
9 A" 1311 1247   5 A"   1242  
10 A" 560 532   -44 A"   576  
11 A" 402 383   -25 A"   408  
12 A" 120 114   -77 A"   191  
The calculated vibrational frequencies were scaled by 0.9513

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.