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Compare vibrational frequencies in CCCBDB for HClO4 (perchloric acid)

TPSSh/6-31G(2df,p)

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3693 3564   7 A'   3557  
2 A' 1320 1273   -34 A'   1307  
3 A' 1191 1149   -31 A'   1180  
4 A' 1023 987   -51 A'   1038  
5 A' 698 673   -38 A'   711  
6 A' 539 521   -48 A'   569  
7 A' 519 501   -47 A'   548  
8 A' 383 369   -36 A'   405  
9 A" 1250 1207   -35 A"   1242  
10 A" 546 527   -49 A"   576  
11 A" 390 376   -32 A"   408  
12 A" 144 139   -52 A"   191  
The calculated vibrational frequencies were scaled by 0.965

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.