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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For HSe+ atoms 1 and 2

For HSe+ (selenium monohydride cation)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0001 0.0001 -0.0001 0.0010 0.0062 0.0019 0.0020 0.0045 0.0030 0.0089 0.0053 -0.0002 0.0014 0.0060 0.0055 0.0020 0.0078 0.0071 0.0011 0.0072
MP3=FULL         -0.0052   0.0027       0.0043 -0.0003 0.0012 0.0044         0.0016 0.0061
MP4=FULL   0.0001     0.0008       0.0044   0.0048   0.0013 0.0060   0.0018 0.0070   0.0017 0.0071
B2PLYP=FULL 0.0000 0.0000 -0.0000 0.0003 0.0002 0.0007 0.0007 0.0004 0.0006 0.0026 0.0017 -0.0001 0.0004 0.0020   0.0005 0.0026   0.0005 0.0024
Quadratic configuration interaction QCISD(T)=FULL         0.0008           0.0045     0.0046   0.0018 0.0068   0.0017 0.0071
Coupled Cluster CCSD=FULL         0.0009         0.0090 0.0044 -0.0000 0.0013 0.0053 0.0045 0.0018 0.0070   0.0017 0.0064
CCSD(T)=FULL         0.0008           0.0044 -0.0001   0.0045 0.0044 0.0018 0.0068 0.0063 0.0017 0.0071
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

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