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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For HF+ atoms 1 and 2

For HF+ (hydrogen fluoride cation)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0000 0.0000 0.0000 0.0000 0.0001 0.0003 0.0002 0.0006 0.0004 0.0000 0.0008 0.0001 0.0003 0.0012 0.0013 0.0002 0.0022 0.0015 0.0002 0.0022
MP3=FULL         0.0320   -0.0001                          
B2PLYP=FULL 0.0000 0.0000 0.0000 0.0000 0.0000 0.0001 0.0001 0.0001 0.0001 0.0001 0.0002 0.0000 0.0001 0.0005   0.0001 0.0006   0.0001 0.0007
Quadratic configuration interaction QCISD(T)=FULL         0.0001           0.0009   0.0003 0.0015   0.0001 0.0021   0.0002 0.0024
Coupled Cluster CCSD=FULL         0.0001         0.0000 0.0009 0.0002 0.0003 0.0019 0.0011 0.0002 0.0016 0.0014 0.0002 0.0019
CCSD(T)=FULL         0.0001           0.0009 0.0001 0.0003 0.0013 0.0010 0.0001 0.0021 0.0014 0.0002 0.0024
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ daug-cc-pVDZ daug-cc-pVTZ

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