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Bond Length differences between FULL (all electrons correlated) and FROZEN core

Such as MP2=Frozen and MP2=Full
17 10 27 16 27

For F2 atoms 1 and 2

For F2 (Fluorine diatomic)
Bond length differences (full - frozen) in Å. Mouse over a difference for the bond length with full correlation.
Methods with standard basis sets
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) 6-311+G(3df,2pd) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pCVDZ cc-pCVTZ cc-pCVQZ Sadlej_pVTZ daug-cc-pVDZ daug-cc-pVTZ
Moller Plesset perturbation MP2=FULL 0.0000 0.0000 0.0000 -0.0005 -0.0136 0.0002 0.0004 -0.0203 0.0006 -0.0097 0.0016 0.0016 0.0008 -0.0003 0.0019 0.0018 0.0000 0.0025 0.0026 0.0004 0.0014 0.0015 0.0003 0.0004 0.0036
MP3=FULL   0.0001 0.0001 0.0000 0.0135 0.0003 0.0163 0.0009 0.0009 0.0006 0.0015   0.0007 0.0001 0.0021   0.0001 0.0036   0.0004 0.0013 0.0015   0.0003 0.0037
MP4=FULL 0.0000 0.0000 0.0000 0.0001 0.0002 0.0003 0.0005 -0.0001 0.0007 0.0006 0.0016 0.0016 0.0007 0.0001 0.0021 0.0017 0.0002 0.0041 0.0027 0.0004 0.0009 0.0010   0.0004 0.0043
B2PLYP=FULL 0.0000 0.0011 0.0000 -0.0000 0.0148 0.0001 0.0201 0.0002 0.0002 0.0001 0.0006   0.0002 0.0000 0.0000   0.0000 0.0008   0.0001 0.0003 0.0006   0.0001 0.0008
Quadratic configuration interaction QCISD(T)=FULL         0.0002   0.0005       0.0016     0.0001 0.0022 0.0018 0.0002 0.0041 0.0028 0.0005 0.0012 0.0013   0.0004 0.0043
Coupled Cluster CCSD=FULL 0.0000 0.0002 0.0002 0.0001 0.0003 0.0004 0.0005 0.0009 0.0009 0.0006 0.0019 0.0019 0.0009 0.0002 0.0023 0.0021 0.0003 0.0039 0.0029 0.0008 0.0018 0.0020   0.0005 0.0040
CCSD(T)=FULL 0.0000 -0.0005 0.0000 0.0000 -0.0003 -0.0003 0.0004 0.0005 0.0007 0.0006 0.0017 0.0017 0.0008 -0.0001 0.0021 0.0018 -0.0003 0.0041 0.0028 0.0005 0.0012 0.0014   0.0004 0.0043
STO-3G 3-21G 3-21G* 6-31G 6-31G* 6-31G** 6-31+G** 6-311G* 6-311G** 6-31G(2df,p) 6-311+G(3df,2p) 6-311+G(3df,2pd) TZVP cc-pVDZ cc-pVTZ cc-pVQZ aug-cc-pVDZ aug-cc-pVTZ aug-cc-pVQZ cc-pCVDZ cc-pCVTZ cc-pCVQZ Sadlej_pVTZ daug-cc-pVDZ daug-cc-pVTZ

f2q1.gif