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	hartrees
Energy at 0K	-679.269835
Energy at 298.15K	-679.273759
HF Energy	-678.202097
Nuclear repulsion energy	273.609273

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A'	3231	3060	18.80
2	A'	1424	1349	90.37
3	A'	1184	1121	227.26
4	A'	889	842	194.15
5	A'	810	767	104.32
6	A'	536	507	104.26
7	A'	478	452	68.71
8	A'	378	358	55.25
9	A'	266	251	0.99
10	A"	3342	3166	10.31
11	A"	997	944	249.74
12	A"	840	796	0.00
13	A"	457	433	0.12
14	A"	373	353	19.69
15	A"	202	192	1.31

Atom	x (Å)	y (Å)	z (Å)
P1	-0.022	0.120	0.000
C2	-0.494	1.657	0.000
F3	1.469	-0.402	0.000
F4	-0.494	-0.695	1.242
F5	-0.494	-0.695	-1.242
H6	-0.520	2.199	-0.934
H7	-0.520	2.199	0.934

	P1	C2	F3	F4	F5	H6	H7
P1		1.6077	1.5797	1.5585	1.5585	2.3324	2.3324
C2	1.6077		2.8446	2.6600	2.6600	1.0797	1.0797
F3	1.5797	2.8446		2.3407	2.3407	3.4047	3.4047
F4	1.5585	2.6600	2.3407		2.4834	3.6205	2.9104
F5	1.5585	2.6600	2.3407	2.4834		2.9104	3.6205
H6	2.3324	1.0797	3.4047	3.6205	2.9104		1.8674
H7	2.3324	1.0797	3.4047	2.9104	3.6205	1.8674

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	119.126	P1	C2	H7	119.126
C2	P1	F3	126.362	C2	P1	F4	114.295
C2	P1	F5	114.295	F3	P1	F4	96.463
F3	P1	F5	96.463	F4	P1	F5	105.634
H6	C2	H7	119.712

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: MP2=FULL/6-311G*

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: MP2=FULL/6-311G*

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)