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18 10 26 16 45

CCSD(T)=FULL/cc-pVDZ for rSiH

Histogram of Bond length differences (in Å) vs number of species


Differences greater than 0.055 are in the 0.055 bin. Differences less than -0.005 are in the -0.005 bin.

histogram chart 10
histogram chart 8
histogram chart 6
histogram chart 4 histogram chart
histogram chart 2 histogram chart histogram chart histogram chart
histogram chart 0 histogram chart histogram chart histogram chart histogram chart histogram chart histogram chart
-0.005 0.000 0.005 0.010 0.015 0.020 0.025 0.030 0.035 0.040 0.045 0.050 0.055
bond length difference calc. - exp. (Å)

  Species Name Difference (Å)
Most negative difference SiH2Cl2 dichlorosilane-0.001
Most positive difference SiH3 Silyl radical0.024

Bond lengths
Click on entry for experimental details.

Species Name Experimental (Å) Difference (Å)
SiH2Cl2 dichlorosilane 1.480 -0.001
SiH3Br bromosilane 1.481 0.005
HSiCl Chlorosilylene 1.525 0.008
SiH3F monofluorosilane 1.476 0.009
SiH3Cl chlorosilane 1.475 0.010
SiH4 Silane 1.480 0.010
HSiBr monobromosilylene 1.518 0.014
SiH2F2 difluorosilane 1.462 0.015
SiHF3 trifluorosilane 1.449 0.015
SiH+ silicon monohydride cation 1.504 0.016
SiH3+ Silyl cation 1.460 0.016
SiH2 silicon dihydride 1.514 0.018
Si2H2 disilyne 1.668 0.019
SiH Silylidyne 1.520 0.019
Si2H6 disilane 1.470 0.024
SiH3 Silyl radical 1.468 0.024