III.D.11. |
Calculated Proton Affinity
Name | Species | Species | Name | |
---|---|---|---|---|
2-Propanamine, 2-methyl- | C(CH3)3NH2 | → | NC4H12+ | tetramethyl ammonium cation |
Bonding changes |
---|
Bond type H-C changed by +3 Bond type C-N changed by +3 Bond type H-N lost 2 Bond type C-C lost 3 |
Proton Affinities in kJ/mol
Proton Affinities in kJ/mol
STO-3G | 3-21G | 3-21G* | 6-31G | 6-31G* | 6-31+G** | 6-311G* | 6-311G** | 6-31G(2df,p) | 6-311+G(3df,2p) | TZVP | cc-pVDZ | cc-pVTZ | aug-cc-pVDZ | aug-cc-pVTZ | daug-cc-pVTZ | ||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
hartree fock | HF | 911 | 893 | 898 | 896 | ||||||||||||
density functional | BLYP | 913 | |||||||||||||||
B3LYP | 882 | 876 | 866 | 873 | |||||||||||||
B3PW91 | 1112 | 880 | |||||||||||||||
mPW1PW91 | 1110 | 934 | 877 | ||||||||||||||
M06-2X | 931 | 896 | |||||||||||||||
PBEPBE | 1115 | 935 | 900 | 855 | |||||||||||||
PBE1PBE | 898 | ||||||||||||||||
HSEh1PBE | 930 | 898 | 873 | ||||||||||||||
TPSSh | 925 | 897 | 919 | 900 | |||||||||||||
wB97X-D | 944 | 909 | 881 | 886 | 882 | 881 | 884 | 879 | |||||||||
B97D3 | 959 | 926 | 895 | 899 | 892 | 893 | 896 | 890 | |||||||||
STO-3G | 3-21G | 3-21G* | 6-31G | 6-31G* | 6-31+G** | 6-311G* | 6-311G** | 6-31G(2df,p) | 6-311+G(3df,2p) | TZVP | cc-pVDZ | cc-pVTZ | aug-cc-pVDZ | aug-cc-pVTZ | daug-cc-pVTZ | ||
Moller Plesset perturbation | MP2 | 1174 | 896 | 878 | 893 | 881 | |||||||||||
MP2=FULL | 878 | ||||||||||||||||
MP3=FULL | 900 | 888 | |||||||||||||||
STO-3G | 3-21G | 3-21G* | 6-31G | 6-31G* | 6-31+G** | 6-311G* | 6-311G** | 6-31G(2df,p) | 6-311+G(3df,2p) | TZVP | cc-pVDZ | cc-pVTZ | aug-cc-pVDZ | aug-cc-pVTZ | daug-cc-pVTZ |
Proton Affinities in kJ/mol
CEP-31G | CEP-31G* | CEP-121G | CEP-121G* | LANL2DZ | SDD | cc-pVTZ-PP | aug-cc-pVTZ-PP | Def2TZVPP | ||
---|---|---|---|---|---|---|---|---|---|---|
hartree fock | HF | 897 | ||||||||
density functional | B3LYP | 875 | ||||||||
PBEPBE | 863 | |||||||||
Moller Plesset perturbation | MP2 | 871 |