Listing of experimental geometry data for F3PO (Phosphoryl fluoride)
Rotational Constants (cm-1)
See section I.F.4 to change rotational constant units
Rotational Constants from
1952Wil/She:164
Calculated rotational constants
for F3PO (Phosphoryl fluoride).
Point Group C3v
Internal coordinates (distances (r) in Å) (angles (a) in degrees) (dihedrals (d) in degrees)
Bond descriptions
Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond
| Bond Type |
Count |
| O=P |
1 |
| F-P |
3 |
| Atom |
x (Å) |
y (Å) |
z (Å) |
| P1
| 0.0000
| 0.0000
| 0.1407
|
| O2
| 0.0000
| 0.0000
| 1.5767
|
| F3
| 0.0000
| 1.3609
| -0.5453
|
| F4
| 1.1786
| -0.6805
| -0.5453
|
| F5
| -1.1786
| -0.6805
| -0.5453
|
Atom - Atom Distances (Å)
| |
P1 |
O2 |
F3 |
F4 |
F5 |
| P1 | | 1.4360 | 1.5240 | 1.5240 | 1.5240 |
|---|
| O2 | 1.4360 | | 2.5209 | 2.5209 | 2.5209 |
|---|
| F3 | 1.5240 | 2.5209 | | 2.3571 | 2.3571 |
|---|
| F4 | 1.5240 | 2.5209 | 2.3571 | | 2.3571 |
|---|
| F5 | 1.5240 | 2.5209 | 2.3571 | 2.3571 | |
|---|
Calculated geometries
for F3PO (Phosphoryl fluoride).
References
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| squib |
reference |
DOI |
| 1952Wil/She:164 |
Williams, Q.; Sheridan, J.; Gordy, W. "Microwave Spectra and molecular Structures of POF3, PSF3, POCl3, and PSCl3." Journal of Chemical Physics. 20, 164-167 (1952) |
10.1063/1.1700162 |
| 1976Hellwege(II/7) |
Hellwege, KH and AM Hellwege (ed.). Landolt-Bornstein: Group II: Atomic and Molecular Physics Volume 7: Structure Data of Free Polyatomic Molecules. Springer-Verlag. Berlin. 1976. |
|
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