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II.A.3. (XII.A.1.)

Listing of experimental geometry data for SiCl3CH3 (methyltrichlorosilane)

Rotational Constants (cm-1)
See section I.F.4 to change rotational constant units
A B C
  0.05903  
Rotational Constants from 1977Tak/Mat:1633
Calculated rotational constants for SiCl3CH3 (methyltrichlorosilane).

Point Group C3v

Internal coordinates (distances (r) in Å) (angles (a) in degrees) (dihedrals (d) in degrees)
Description Value Connectivity Reference Comment
Atom 1 Atom 2 Atom 3 Atom 4
rCSi 1.848 1 2 1998Kuc
rSiCl 2.026 1 3 1998Kuc
aCSiCl 110.3 2 1 3 1998Kuc
aClSiCl 108.6 3 1 4 1998Kuc
picture of methyltrichlorosilane

Bond descriptions
Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond
Bond Type Count
C-Si 1
H-C 3
Si-Cl 3

Atom x (Å) y (Å) z (Å)

Atom - Atom Distances (Å)
 

Calculated geometries for SiCl3CH3 (methyltrichlorosilane).


References
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squib reference DOI
1977Tak/Mat:1633 H Takeo, C Matsumura "The Microwave Spectra, Molecular Structures, and Quadrupole Coupling Constants of Methyltrichlorosilane and Trichlorosilane" Bulletin of the Chemical Society of Japan Vol. 50 (1977) No. 6 P 1633-1634 10.1246/bcsj.50.1633
1998Kuc K Kuchitsu(ed) "Structure of Free Polyatomic Molecules - Basic Data" Springer, Berlin, 1998  

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