IV.D.4. (XII.A.2.) |
Compare Bonds
18 10 19 16 31G3 for rPCl
Histogram of Bond length differences (in Å) vs number of species
Differences greater than 0.055 are in the 0.055 bin. Differences less than -0.005 are in the -0.005 bin.
10 | ||||||||||||||||||||||||||||||||||||||||
8 | ||||||||||||||||||||||||||||||||||||||||
6 | ||||||||||||||||||||||||||||||||||||||||
4 | ||||||||||||||||||||||||||||||||||||||||
2 | ||||||||||||||||||||||||||||||||||||||||
0 | ||||||||||||||||||||||||||||||||||||||||
-0.005 | 0.000 | 0.005 | 0.010 | 0.015 | 0.020 | 0.025 | 0.030 | 0.035 | 0.040 | 0.045 | 0.050 | 0.055 | ||||||||||||||||||||||||||||
bond length difference calc. - exp. (Å) |
Species | Name | Difference (Å) | |
---|---|---|---|
Most negative difference | PCl3 | Phosphorus trichloride | 0.005 |
Most positive difference | PCl | phosphorus chloride | 0.026 |
Bond lengths
Click on entry for experimental details.
Species | Name | Experimental (Å) | Difference (Å) |
---|---|---|---|
PCl3 | Phosphorus trichloride | 2.043 | 0.005 |
PCl | phosphorus chloride | 2.018 | 0.005 |
OPCl | Phosphorus oxychloride | 2.059 | 0.005 |
PCl5 | Phosphorus pentachloride | 2.020 | 0.006 |
Cl3PO | Phosphoryl chloride | 1.989 | 0.009 |
PCl5 | Phosphorus pentachloride | 2.124 | 0.021 |
PCl | phosphorus chloride | 2.018 | 0.026 |