IV.D.4. (XII.A.2.) |
Compare Bonds
18 10 19 16 31PM6 for rPH
Histogram of Bond length differences (in Å) vs number of species
Differences greater than 0.055 are in the 0.055 bin. Differences less than -0.005 are in the -0.005 bin.
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8 | ||||||||||||||||||||||||||||||||||||||||
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4 | ||||||||||||||||||||||||||||||||||||||||
2 | ||||||||||||||||||||||||||||||||||||||||
0 | ||||||||||||||||||||||||||||||||||||||||
-0.005 | 0.000 | 0.005 | 0.010 | 0.015 | 0.020 | 0.025 | 0.030 | 0.035 | 0.040 | 0.045 | 0.050 | 0.055 | ||||||||||||||||||||||||||||
bond length difference calc. - exp. (Å) |
Species | Name | Difference (Å) | |
---|---|---|---|
Most negative difference | PH2 | Phosphino radical | 0.025 |
Most positive difference | PH | phosphorus monohydride | 0.047 |
Bond lengths
Click on entry for experimental details.
Species | Name | Experimental (Å) | Difference (Å) |
---|---|---|---|
PH2 | Phosphino radical | 1.428 | 0.025 |
PH+ | phosphorus monohydride cation | 1.435 | 0.029 |
PH | phosphorus monohydride | 1.422 | 0.031 |
CH3PH2 | Methyl phosphine | 1.423 | 0.031 |
PH | phosphorus monohydride | 1.422 | 0.032 |
PH3 | Phosphine | 1.421 | 0.032 |
CH2PH | Phosphaethene | 1.420 | 0.039 |
CH2PH | Phosphaethene | 1.420 | 0.039 |
P2H4 | Diphosphine | 1.417 | 0.040 |
P2H4 | Diphosphine | 1.414 | 0.043 |
HPO | Hydrogen phosphorus oxide | 1.433 | 0.044 |
PH | phosphorus monohydride | 1.422 | 0.047 |