IV.D.4. (XII.A.2.) |
Compare Bonds
18 10 19 16 31G2 for rPH
Histogram of Bond length differences (in Å) vs number of species
Differences greater than 0.025 are in the 0.025 bin. Differences less than -0.035 are in the -0.035 bin.
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8 | ||||||||||||||||||||||||||||||||||||||||
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4 | ||||||||||||||||||||||||||||||||||||||||
2 | ||||||||||||||||||||||||||||||||||||||||
0 | ||||||||||||||||||||||||||||||||||||||||
-0.035 | -0.030 | -0.025 | -0.020 | -0.015 | -0.010 | -0.005 | 0.000 | 0.005 | 0.010 | 0.015 | 0.020 | 0.025 | ||||||||||||||||||||||||||||
bond length difference calc. - exp. (Å) |
Species | Name | Difference (Å) | |
---|---|---|---|
Most negative difference | PH+ | phosphorus monohydride cation | -0.031 |
Most positive difference | HPO | Hydrogen phosphorus oxide | -0.002 |
Bond lengths
Click on entry for experimental details.
Species | Name | Experimental (Å) | Difference (Å) |
---|---|---|---|
PH+ | phosphorus monohydride cation | 1.435 | -0.031 |
PH2 | Phosphino radical | 1.428 | -0.021 |
CH3PH2 | Methyl phosphine | 1.423 | -0.019 |
PH3 | Phosphine | 1.421 | -0.018 |
P2H4 | Diphosphine | 1.417 | -0.015 |
P2H4 | Diphosphine | 1.414 | -0.013 |
PH | phosphorus monohydride | 1.422 | -0.012 |
PH | phosphorus monohydride | 1.422 | -0.012 |
PH | phosphorus monohydride | 1.422 | -0.012 |
CH2PH | Phosphaethene | 1.420 | -0.011 |
HPO | Hydrogen phosphorus oxide | 1.433 | -0.002 |