IV.D.4. (XII.A.2.) |
Compare Bonds
18 10 19 16 31G4 for rPH
Histogram of Bond length differences (in Å) vs number of species
Differences greater than 0.055 are in the 0.055 bin. Differences less than -0.005 are in the -0.005 bin.
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8 | ||||||||||||||||||||||||||||||||||||||||
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4 | ||||||||||||||||||||||||||||||||||||||||
2 | ||||||||||||||||||||||||||||||||||||||||
0 | ||||||||||||||||||||||||||||||||||||||||
-0.005 | 0.000 | 0.005 | 0.010 | 0.015 | 0.020 | 0.025 | 0.030 | 0.035 | 0.040 | 0.045 | 0.050 | 0.055 | ||||||||||||||||||||||||||||
bond length difference calc. - exp. (Å) |
Species | Name | Difference (Å) | |
---|---|---|---|
Most negative difference | PH2 | Phosphino radical | -0.002 |
Most positive difference | HPO | Hydrogen phosphorus oxide | 0.036 |
Bond lengths
Click on entry for experimental details.
Species | Name | Experimental (Å) | Difference (Å) |
---|---|---|---|
PH2 | Phosphino radical | 1.428 | -0.002 |
CH3PH2 | Methyl phosphine | 1.423 | -0.001 |
PH3 | Phosphine | 1.421 | -0.001 |
PH+ | phosphorus monohydride cation | 1.435 | 0.002 |
P2H4 | Diphosphine | 1.417 | 0.004 |
P2H4 | Diphosphine | 1.414 | 0.005 |
PH | phosphorus monohydride | 1.422 | 0.008 |
PH | phosphorus monohydride | 1.422 | 0.010 |
PH | phosphorus monohydride | 1.422 | 0.010 |
CH2PH | Phosphaethene | 1.420 | 0.010 |
HPO | Hydrogen phosphorus oxide | 1.433 | 0.036 |