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Compare vibrational frequencies in CCCBDB for C3O (Tricarbon monoxide)

PBEPBE/6-31G

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 Σ 2257 2226   -31 Σ   2257  
2 Σ 1838 1813   -94 Σ   1907  
3 Σ 919 906   -29 Σ   935  
4 Π 569 561   -20 Π   581  
5 Π 190 188   79 Π   109  
The calculated vibrational frequencies were scaled by 0.9862

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.