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Compare vibrational frequencies in CCCBDB for H3O+ (hydronium cation)

CID/3-21G

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A1 3552 3309   -182 A1   3491  
2 A1 334 311   -643 A1   954  
3 E 3685 3433   -103 E   3536  
4 E 1729 1611   -15 E   1626  
The calculated vibrational frequencies were scaled by 0.9316

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.