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Compare vibrational frequencies in CCCBDB for H2CNCN (cyanamide, methylene)

mPW1PW91/6-311G**

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A' 3213 3074   -63 A'   3137  
2 A' 3090 2957   749 A'   2208  
3 A' 2346 2244   623 A'   1621  
4 A' 1730 1655   199 A'   1456  
5 A' 1508 1442           
6 A' 1230 1177   -38 A'   1215  
7 A' 978 936           
8 A' 638 611           
9 A' 254 243           
10 A" 1105 1057   -33 A"   1090  
11 A" 787 753           
12 A" 383 366           
The calculated vibrational frequencies were scaled by 0.9567

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.