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Compare vibrational frequencies in CCCBDB for H2O2 (Hydrogen peroxide)

MP2=FULL/6-31G

18 11 26 13 55
Frequency in cm-1
  Calculated   Experimental
Mode Number Symmetry Frequency Scaled
Frequency
Harm.
diff
Fund.
diff
Symmetry Harmonic
Frequency
Fundamental
Frequency
Comment
1 A 3578 3400   -199 A   3599  
2 A 1440 1369   -33 A   1402  
3 A 797 757   -120 A   877  
4 A 159 151   -220 A   371  
5 B 3593 3413   -195 B   3608  
6 B 1131 1075   -191 B   1266  
The calculated vibrational frequencies were scaled by 0.9501

See section Calculated; Vibrations; Scale Factors; Set scaling factors to change the scale factors used here.
See section Calculated; Vibrations; Scale Factors; Calculate a scale factor to determine the least squares best scaling factor.
See section Calculated; Vibrations; Scale Factors; Scale factor uncertainty for information on where the above scaling factor is from.